Electrically conductive metal–organic frameworks
Metal–organic frameworks (MOFs) are intrinsically porous extended solids formed by
coordination bonding between organic ligands and metal ions or clusters. High electrical …
coordination bonding between organic ligands and metal ions or clusters. High electrical …
Radical ligand-containing single-molecule magnets
Single-molecule magnets represent the ultimate size limit for spin-based information storage
and processing; however, such applications require large spin relaxation barriers and …
and processing; however, such applications require large spin relaxation barriers and …
Metallic conductivity in a two-dimensional cobalt dithiolene metal–organic framework
Two-dimensional (2D) metal–organic frameworks (MOFs) have received a great deal of
attention due to their relatively high charge carrier mobility and low resistivity. Here we report …
attention due to their relatively high charge carrier mobility and low resistivity. Here we report …
Two-dimensional metal–organic surfaces for efficient hydrogen evolution from water
AJ Clough, JW Yoo, MH Mecklenburg… - Journal of the …, 2015 - ACS Publications
Hydrogen production through the reduction of water has emerged as an important strategy
for the storage of renewable energy in chemical bonds. One attractive scenario for the …
for the storage of renewable energy in chemical bonds. One attractive scenario for the …
New avenues for ligand-mediated processes–expanding metal reactivity by the use of redox-active catechol, o-aminophenol and o-phenylenediamine ligands
DLJ Broere, R Plessius, JI van der Vlugt - Chemical Society Reviews, 2015 - pubs.rsc.org
Redox-active ligands have evolved from being considered spectroscopic curiosities–
creating ambiguity about formal oxidation states in metal complexes–to versatile and useful …
creating ambiguity about formal oxidation states in metal complexes–to versatile and useful …
Redox-active ligands: Recent advances towards their incorporation into coordination polymers and metal-organic frameworks
B Ding, MB Solomon, CF Leong… - Coordination Chemistry …, 2021 - Elsevier
Over the past three decades, the field of coordination polymers (CPs) and metal–organic
frameworks (MOFs) has developed rapidly due to the potential applications of these …
frameworks (MOFs) has developed rapidly due to the potential applications of these …
High Electrical Conductivity in Ni3(2,3,6,7,10,11-hexaiminotriphenylene)2, a Semiconducting Metal–Organic Graphene Analogue
D Sheberla, L Sun, MA Blood-Forsythe… - Journal of the …, 2014 - ACS Publications
Reaction of 2, 3, 6, 7, 10, 11-hexaaminotriphenylene with Ni2+ in aqueous NH3 solution
under aerobic conditions produces Ni3 (HITP) 2 (HITP= 2, 3, 6, 7, 10, 11 …
under aerobic conditions produces Ni3 (HITP) 2 (HITP= 2, 3, 6, 7, 10, 11 …
Nitrate and periplasmic nitrate reductases
The nitrate anion is a simple, abundant and relatively stable species, yet plays a significant
role in global cycling of nitrogen, global climate change, and human health. Although it has …
role in global cycling of nitrogen, global climate change, and human health. Although it has …
Cation-dependent intrinsic electrical conductivity in isostructural tetrathiafulvalene-based microporous metal–organic frameworks
Isostructural metal–organic frameworks (MOFs) M2 (TTFTB)(M= Mn, Co, Zn, and Cd;
H4TTFTB= tetrathiafulvalene tetrabenzoate) exhibit a striking correlation between their …
H4TTFTB= tetrathiafulvalene tetrabenzoate) exhibit a striking correlation between their …
Radical‐type reactivity and catalysis by single‐electron transfer to or from redox‐active ligands
JI van der Vlugt - Chemistry–A European Journal, 2019 - Wiley Online Library
Controlled ligand‐based redox‐activity and chemical non‐innocence are rapidly gaining
importance for selective (catalytic) processes. This Concept aims to provide an overview of …
importance for selective (catalytic) processes. This Concept aims to provide an overview of …