Strategies for accessing photosensitizers with extreme redox potentials

D Kim, TS Teets - Chemical Physics Reviews, 2022 - pubs.aip.org
Photoredox catalysis has been prominent in many applications, including solar fuels,
organic synthesis, and polymer chemistry. Photocatalytic activity directly depends on the …

Non-covalent intramolecular interactions through ligand-design promoting efficient photoluminescence from transition metal complexes

IO Koshevoy, M Krause, A Klein - Coordination Chemistry Reviews, 2020 - Elsevier
Ligand design allows arranging ligand entities and functional groups in order to generate a
plethora of non-covalent interactions such as π stacking, H bridging, and Lewis acid-base …

Molecular Design Principles to Elongate the Metal-to-Ligand Charge Transfer Excited-State Lifetimes of Square-Planar Nickel (II) Complexes

T Ogawa, N Sinha, B Pfund, A Prescimone… - Journal of the …, 2022 - ACS Publications
Square-planar NiII complexes and their electronically excited states play key roles in cross-
coupling catalysis and could offer new opportunities to complement well-known …

High triplet energy iridium (III) isocyanoborato complex for photochemical upconversion, photoredox and energy transfer catalysis

L Schmid, F Glaser, R Schaer… - Journal of the American …, 2022 - ACS Publications
Cyclometalated Ir (III) complexes are often chosen as catalysts for challenging photoredox
and triplet–triplet-energy-transfer (TTET) catalyzed reactions, and they are of interest for …

High‐Sulfur Loading and Single Ion‐Selective Membranes for High‐Energy and Durable Decoupled Aqueous Batteries

X Zhang, B Zhang, JL Yang, J Wu, H Jiang… - Advanced …, 2024 - Wiley Online Library
The decoupled battery design is promising for breaking the energy density limit of traditional
aqueous batteries. However, the complex battery configuration and low‐selective separator …

Photostable ruthenium (II) isocyanoborato luminophores and their use in energy transfer and photoredox catalysis

L Schmid, C Kerzig, A Prescimone, OS Wenger - JACS Au, 2021 - ACS Publications
Ruthenium (II) polypyridine complexes are among the most popular sensitizers in
photocatalysis, but they face some severe limitations concerning accessible excited-state …

Lewis‐Pairing‐Induced Electrochemiluminescence Enhancement from Electron Donor‐Acceptor Diads Decorated with Tris (pentafluorophenyl) borane as an …

T Ikeda, K Tahara, R Ishimatsu, T Ono… - Angewandte Chemie …, 2023 - Wiley Online Library
This study reports an effective peripheral decoration of organic donor‐acceptor diads with B
(C6F5) 3 for stabilizing electrogenerated radical ions. By employing a common p‐type …

Borylation in the Second Coordination Sphere of FeII Cyanido Complexes and Its Impact on Their Electronic Structures and Excited-State Dynamics

L Schmid, P Chábera, I Rüter, A Prescimone… - Inorganic …, 2022 - ACS Publications
Second coordination sphere interactions of cyanido complexes with hydrogen-bonding
solvents and Lewis acids are known to influence their electronic structures, whereby the non …

Bis-cyclometalated iridium complexes with chelating dicarbene ancillary ligands

H Na, A Maity, R Morshed, TS Teets - Organometallics, 2017 - ACS Publications
In this work, we report that covalent postsynthetic modification can be used for the
preparation of a class of bis-cyclometalated iridium complexes featuring Chugaev-type …

Combined Nucleophilic and Electrophilic Functionalization to Optimize Blue Phosphorescence in Cyclometalated Platinum Complexes

YH Nguyen, Y Wu, VQ Dang, C Jiang… - Journal of the American …, 2024 - ACS Publications
Ligand-based functionalization strategies have emerged as powerful approaches to tune
and optimize blue phosphorescence, which can involve nucleophilic addition to coordinated …