Tailoring metal complexes with N-heterocyclic carbene ligands using Electron-Withdrawing Groups: Impact on catalytic activity and property development

RO Pankov, DO Prima, VP Ananikov - Coordination Chemistry Reviews, 2024 - Elsevier
In the field of catalytic chemistry, metal complexes containing N-heterocyclic carbenes
(NHCs) have gained significant attention due to their versatile nature and wide range of …

Mechanistic Investigations on Cp*CoIII-Catalyzed Quinoline Transfer Hydrogenation with Formic Acid

N Garg, P Dahiya, S Mallet-Ladeira, R Poli… - ACS …, 2024 - ACS Publications
The mechanism of the quinoline transfer hydrogenation (TH) by aqueous HCOOH under the
action of [Cp* Co (quinNH2) I]+(A*; quinNH2= 8-aminoquinoline) has been investigated by a …

Ir-catalyzed selective reductive N-formylation and transfer hydrogenation of N-heteroarenes

R Luo, S Wang, Y Liang, J Tong, J Liao… - Organometallics, 2024 - ACS Publications
Selective functionalization has numerous potential applications in the modification of
bioactive compounds and pharmaceuticals. Herein, we advance a new approach for the …

Cyclopentadienone Iridium Bipyridyl Complexes: Acid-Stable Transfer Hydrogenation Catalysts

DP Marron, CM Galvin, RM Waymouth - Organometallics, 2023 - ACS Publications
The synthesis, structure, and reactivity of a series of cyclopentadienone and
hydroxycyclopentadienyl 4, 4′-dimethyl-2, 2′-bipyridine (dmbpy) iridium complexes …

Synthesis and comparative study of (NHC F) PdCl 2 Py and (NHC F) Ni (Cp) Cl complexes: investigation of the electronic properties of NHC ligands and complex …

RO Pankov, IR Tarabrin, AG Son, ME Minyaev… - Dalton …, 2024 - pubs.rsc.org
The electron-donating and electron-accepting properties of N-heterocyclic carbene (NHC)
ligands play a pivotal role in governing their interactions with transition metals, thereby …

Manganese‐Catalysed Transfer Hydrogenation of Quinolines under Mild Conditions

X Chu, G Zhou, M Pang, H Zhang - European Journal of …, 2023 - Wiley Online Library
Herein, an efficient methodology for the homogeneous manganese‐catalysed transfer
hydrogenation of N‐heterocycles by using ammonia‐borane as a hydrogen source under …

A detailed DFT theoretical investigation of the mechanism of quinoline hydrogenation catalyzed by a (1, 5-cyclooctadiene) rhodium (I) complex

M Rosales, F Arrieta, P Baricelli, A Colina, R Izquierdo - Catalysis Today, 2025 - Elsevier
A detailed catalytic cycle for the hydrogenation of quinoline (Q) to 1, 2, 3, 4-
tetrahydroquinoline (THQ) catalyzed by a cationic rhodium complex containing a 1, 5 …

Dosage delivery of chiral ruthenium catalysts using non-ionic surfactants for asymmetric transfer hydrogenation reactions in aqueous media

BÖ Öztürk, M Aklan, SK Şehitoğlu - Reaction Chemistry & Engineering, 2023 - pubs.rsc.org
In this study, non-ionic surfactants, namely Synperonic® F108 and Tween® F108, were
used as media to dissolve [RuCl (p-cymene)(R, R)-Ts-DPEN] for the dosage delivery and …

Six-membered ring systems: pyridines and benzo derivatives

JC Badenock - Progress in Heterocyclic Chemistry, 2023 - Elsevier
Pyridines and benzo derivatives are important classes of heterocyclic compounds that have
attracted significant attention due to their diverse chemical and biological properties. This …