The outstandingly rapid scientific and technological development of metallocene-based
catalysts for olefin polymerization is a perfect example of the successful application of …

This review covers research in olefin polymerization by metallocene catalysts published in
1996. While metallocenes are generally defined as metal complexes with two …

Industrial methods for the manufacture of commodity polyolefins are presently dominated by
gas-and slurryphase processes in which the catalysts are formulated on solid supports.[1] …

This contribution reports an efficient synthesis of the “constrained geometry” group 4
dibenzyl complexes Me2Si (η5-Me4C5)(t BuN) MR2 (CGCMR2, where R= CH2Ph; M= Ti …

The hydroboration of aldehydes and ketones using a silica-supported zirconium catalyst is
reported. Reaction of Zr (NMe2) 4 and mesoporous silica nanoparticles (MSN) provides the …

This contribution describes the synthesis, structures, bonding, and reactivity of neutral (Ox)
2MR2 and cationic (Ox) 2MR+ zirconium and hafnium alkyl complexes which contain …

Monomeric imidozirconocene complexes of the type Cp2 (L) Zr NCMe3 (Cp=
cyclopentadienyl, L= Lewis base) have been shown to activate the carbon− hydrogen bonds …

Since the discovery of ferrocene [1] and the elucidation of its bis-pentahapto sandwich
structure 50 years ago [2], bis-cyclopentadienyl-transition metal andlanthanide metal …

Detailed kinetics of metallocene-catalyzed alkene polymerization reactions are elusive but
essential to understanding the mechanism of these important industrial processes. 1 As …

This contribution describes the implementation of the binuclear organotitanium “constrained
geometry catalysts”(CGCs),(μ-CH2CH2-3, 3 '){(η5-indenyl)[1-Me2Si (t BuN)](TiMe2)} 2 …