Corrole chemistry has witnessed an impressive boost in studies in the last 20 years, thanks
to the possibility of preparing corrole derivatives by simple synthetic procedures. The …

The coordination chemistry of corrole is one of the most intriguing aspects of this contracted
porphyrinoid, for both theoretical and practical reasons. Corrole, in fact, shows a remarkable …

Conspectus Noninnocent ligands do not allow an unambiguous definition of the oxidation
state of a coordinated atom. When coordinated, the ligands also cannot be adequately …

The Gouterman four-orbital model conceptualizes porphyrin UV–visible spectra as
dominated by four frontier molecular orbitals─ two nearly degenerate HOMOs and two …

The question of ligand noninnocence in Cu corroles has long been a topic of discussion.
Presented herein is a Cu K-edge X-ray absorption spectroscopy (XAS) study, which …

A new series of cobalt A3-triarylcorroles were synthesized and the compounds examined as
to their electrochemical and spectroscopic properties in CH2Cl2 or dimethyl sulfoxide …

Hybrid density functional theory (B3LYP) and density matrix renormalization group (DMRG)
theory have been used to quantitatively compare the degree of ligand noninnocence …

A mono-DMSO cobalt meso-CF3 corrole, formulated as (CF3) 3CorCo (DMSO), where (CF3)
3Cor is the trianion of 5, 10, 15-tris (trifluoromethyl) corrole, was synthesized and …

Three mono-CN ligated anionic cobalt A3-triarylcorroles were synthesized and investigated
as to their spectroscopic and electrochemical properties in CH2Cl2, pyridine (Py), and …

High-valent metal-hydroxide species have been implicated as key intermediates in
hydroxylation chemistry catalyzed by heme monooxygenases such as the cytochrome …