Exploration of novel, three‐dimensional chemical space is of growing interest in the drug
discovery community and with this comes the challenge for synthetic chemists to devise new …

The optimization of a palladium-catalyzed Heck–Matsuda reaction using an optimization
algorithm is presented. We modified and implemented the Nelder–Mead method in order to …

Two mononuclear and dinuclear octahedral complexes,[Mn (L1) 2Cl2](1) and [Bi2 (L2)
2Cl8](2)(L1= 2‐(2‐pyridyl)‐4‐methyl‐1, 2‐dihydroquinazoline‐N3‐oxide, L2= 2‐(3‐pyridyl) …

Highly diastereo‐and enantioselective, noncovalent, substrate‐directable Heck
desymmetrizations of cyclopentenyl olefins containing hydroxymethyl and carboxylate …

The Pd-catalyzed decarboxylation and dual C (sp3)–H bond functionalization approaches
have been described for the preparation of symmetrical and unsymmetrical 2, 4 …

A structure selectivity relationship was established by systematically increasing the steric of
the ligands from phenyl substituent to mesityl on the pyridine ring of Pyox and isopropyl to …

exo-Methylene-β-lactams were synthesized in two steps from commercially available 3-
bromo-2-(bromomethyl) propionic acid and reacted with arene diazonium salts in a Heck …

Herein we report the enantioselective Heck‐Matsuda arylation of acyclic E and Z‐alkenyl
aryl ethers. The reactions were carried out under mild conditions affording the …

Typically, metal complexes are constituted of an acceptor metal ion and one or more Iigands
containing the donor atoms. Accordingly, the properties of a metal complex are equally …

Amide functional groups are a structural feature in a vast array of beneficial organic
molecules. This has resulted in a surge in new methodologies developed to enable access …