This Review compiles the evolution, mechanistic understanding, and more recent advances
in enantioselective Pd-catalyzed allylic substitution and decarboxylative and oxidative allylic …

Enantioselective transition metal catalysis is an area very much at the forefront of
contemporary synthetic research. The development of processes that enable the efficient …

Comprehensive computational studies were carried out to explore the mechanisms of
enantioselective Cu/Pd and stereodivergent Cu/Ir dual-catalytic syntheses of α, α …

The stereodivergent synthesis of allene compounds bearing α, β‐adjacent central chiralities
has been realized via the Pd/Cu‐catalyzed dynamic kinetic asymmetric alkylation of racemic …

A stereodivergent Pd/Cu catalyst system has been developed for the unprecedented
dynamic kinetic asymmetric transformation (DyKAT) of racemic unsymmetrical 1, 3 …

Efficient and reliable amplification of chirality has borne its greatest fruit with transition metal-
catalyzed reactions since enantiocontrol may often be imposed by replacing an achiral or …

Highly regio-and enantioselective allylic alkylation has been achieved enabled by the
merger of photoredox and palladium catalysis. In this dual catalytic process, alkyl radicals …

Catalytic enantioselective synthesis of small-molecule building blocks with allylic
stereogenic centers is an important objective in organic synthesis, but preparing this motif …

Many reactions are nowadays catalyzed by a transition metal, which not only accelerates the
reactions but allows, via its ligand (s), a fine control of the chemo-, regio-, and …

Transition metal catalyzed transformations using fluorinating reagents have been developed
extensively for the preparation of synthetically valuable fluorinated targets. This is a topic of …