The cores of many types of polymers, ligands, natural products, and pharmaceuticals
contain biaryl or substituted aromatic structures, and efficient methods of synthesizing these …

Collectively, palladium‐catalyzed coupling reactions represent some of the most powerful
and versatile tools available to synthetic organic chemists. Their widespread popularity …

Suzuki− Miyaura coupling reactions of aryl and heteroaryl halides with aryl-, heteroaryl-and
vinylboronic acids proceed in very good to excellent yield with the use of 2-(2 ', 6 ' …

A general aim of transition metal-catalysed organic synthesis is carbon–carbon (C–C) bond
formation. In this respect, the Pd-catalysed Suzuki–Miyaura (SM) coupling reaction 1 is one …

The completely revised third edition of this four-volume classic is fully updated and now
includes such topics as as CH-activation and multicomponent reactions. It describes the …

Through the use of Pd2 (dba) 3/P (t-Bu) 3 as a catalyst, a wide range of aryl and vinyl
halides, including chlorides, undergo Suzuki cross-coupling with arylboronic acids in very …

Despite advances in the Suzuki–Miyaura cross-coupling process,[1] the need for an
operationally simple and general system remains. The minimum criteria for an optimum …

Until recently, organoboronic acids had found limited use in organic synthesis due to their
low reactivity for ionic reactions. However, it became increasingly clear that they are a …

Palladium complexes supported by (o-biphenyl) P (t-Bu) 2 (3) or (o-biphenyl) PCy2 (4) are
efficient catalysts for the catalytic amination of a wide variety of aryl halides and triflates. Use …

Axial chirality1 was predicted by van't Hoff in his historical paper, 1, 2 which laid the
foundations of stereochemistry. 3 BINOL (1), one of the best known representatives of axially …