Rational synthesis of alkaline earth metal vanadates: Structural origin of MgVO3 honeycomb lattice system and its electrochemical analysis for the detection of …

TSK Sharma, J Jana, KC Bhamu, J Song… - Chemical Engineering …, 2023 - Elsevier
In this study, well-defined alkaline earth metal vanadates, including MgV, CaV, SrV, and
BaV, are synthesized using a simple hydrothermal method, and the crystalline structure …

Synthesis of calcium orthocarbonate, Ca2CO4-Pnma at PT conditions of Earth's transition zone and lower mantle

J Binck, D Laniel, L Bayarjargal… - American …, 2022 - degruyter.com
We show, by single-crystal diffraction studies in laser-heated diamond-anvil cells, that
Ca2CO4 orthocarbonate, which contains CO44− tetrahedra, can be formed already at~ 20 …

Sr[C2O5] is an Inorganic Pyrocarbonate Salt with [C2O5]2– Complex Anions

D Spahr, J König, L Bayarjargal… - Journal of the …, 2022 - ACS Publications
The synthesis of a novel type of carbonate, namely of the inorganic pyrocarbonate salt Sr
[C2O5], which contains isolated [C2O5] 2–-groups, significantly extends the crystal chemistry …

Dense Hydrated Magnesium Carbonate MgCO3·3H2O Phases

BD Botan-Neto, D Santamaria-Perez… - Inorganic …, 2024 - ACS Publications
The study of the structural stability of carbonates under different pressure and temperature
conditions is important for modeling the carbon budget in the Earth's interior and the stability …

Tetrahedrally Coordinated sp3-Hybridized Carbon in Sr2CO4 Orthocarbonate at Ambient Conditions

D Spahr, J Binck, L Bayarjargal, R Luchitskaia… - Inorganic …, 2021 - ACS Publications
We have synthesized the orthocarbonate Sr2CO4, in which carbon is tetrahedrally
coordinated by four oxygen atoms, at moderately high pressures [20 (1) GPa] and high …

Sr3[CO4]O Antiperovskite with Tetrahedrally Coordinated sp3-Hybridized Carbon and OSr6 Octahedra

D Spahr, J König, L Bayarjargal… - Inorganic …, 2021 - ACS Publications
We have synthesized the orthocarbonate Sr3 [CO4] O in a laser-heated diamond anvil cell at
20 and 30 GPa by heating to≈ 3000 (300) K. Afterward, we recovered the orthocarbonate …

Synthesis and crystal structure of acentric anhydrous beryllium carbonate Be (CO 3)

D Spahr, L Bayarjargal, E Bykova, M Bykov… - Chemical …, 2024 - pubs.rsc.org
The anhydrous alkaline earth metal carbonate Be (CO3) was synthesized in a laser-heated
diamond anvil cell at moderate pressures and temperatures (20 (2) GPa and 1500 (200) K) …

Synthesis and Structure of Pb[C2O5]: An Inorganic Pyrocarbonate Salt

D Spahr, J König, L Bayarjargal… - Inorganic …, 2022 - ACS Publications
We have synthesized Pb [C2O5], an inorganic pyrocarbonate salt, in a laser-heated
diamond anvil cell (LH-DAC) at 30 GPa by heating a Pb [CO3]+ CO2 mixture to≈ 2000 …

Novel Calcium sp3 Carbonate CaC2O5-I4̅2d May Be a Carbon Host in Earth's Lower Mantle

J König, D Spahr, L Bayarjargal… - ACS Earth and Space …, 2022 - ACS Publications
CaC2O5-I 4̅2 d was obtained by reacting CO2 and CaCO3 at lower Earth mantle
pressures and temperatures ranging between 34 and 45 GPa and between 2000 and 3000 …

Ca3[C2O5]2[CO3] is a pyrocarbonate which can be formed at pT-conditions prevalent in the Earth's transition zone

D Spahr, L Bayarjargal, M Bykov, L Brüning… - Communications …, 2024 - nature.com
Understanding the fate of subducted carbonates is a prerequisite for the elucidation of the
Earth's deep carbon cycle. Here we show that the concomitant presence of Ca [CO3] with …