Denitrative Functionalization of Nitroarenes: Recent Progress and Future Perspectives

H Li, Z Lei, X Yang, Y Xiao, Y Yin, J Du… - European Journal of …, 2024 - Wiley Online Library
Nitroarenes are fundamental feedstocks in the chemical industry. Their relatively inert C−
NO2 bond allows for late‐stage modifications of molecules and exhibits complete …

Synthetic exploration of electrophilic xanthylation via powerful N-xanthylphthalimides

S Wang, L Yang, F Liang, Y Zhong, X Liu, Q Wang… - Chemical …, 2023 - pubs.rsc.org
Organic xanthates are broadly applied as synthetic intermediates and bioactive molecules in
synthetic chemistry. Electrophilic xanthylation represents a promising approach but has …

Divergent Construction of Thiochromanes and N-Arylbutanamides via Arylthiodifluoromethyl Radical-Triggered Cascade of Alkenes

Y Sun, SP Zhang, WC Yang - The Journal of Organic Chemistry, 2023 - ACS Publications
A strategy utilizing silver-catalyzed oxidative decarboxylation radical cascade cyclization of
arylthiodifluoroacetic acids with alkenes for the simple and efficient preparation of …

Halogen Bond-Activated Visible-Light-Mediated Regioselective C–H Arylation of 2-Phenylimidazo-[1,2-a]pyridines

I Kazi, A Nandy, R Selvam, G Sekar - The Journal of Organic …, 2022 - ACS Publications
An efficient method for transition metal-free halogen bond-assisted regioselective C–H
arylation of 2-phenylimidazo-[1, 2-a] pyridines under visible-light condition has been …

Denitrative Formal [5+ 1] Cycloaddition of 1‐(2‐Nitrophenyl)‐2‐Yn‐1‐Ones with Thioacetamide under Transition‐Metal‐Free Conditions: Synthesis of Thiochromen‐4 …

Y Xu, W Wang, H Fan, X Liao, Z Yang… - European Journal of …, 2024 - Wiley Online Library
A new strategy for thiochromen‐4‐one synthesis that relies on the denitrative formal [5+ 1]
cycloaddition of 1‐(2‐nitrophenyl)‐2‐yn‐1‐ones with thioacetamide is described. Achieved …

Direct dehydroxy (sulfhydryl) xanthylation of alcohols and thiols

D Shan, M Jiang, F Liang, Y Zhong… - Organic Chemistry …, 2024 - pubs.rsc.org
Alkyl xanthates are broadly applied as synthetic intermediates for expedient access to a
range of functional group derivatives in synthetic chemistry. Dehydroxyxanthylations of …

Palladium-Catalyzed Multicomponent Cascade Reaction of 3-Hydroxypropionitrile: Synthesis of Substituted Dihydrochalcones

J Zheng, Q Wang, Y Li, H Zheng, C Hu… - The Journal of …, 2023 - ACS Publications
Direct access to substituted dihydrochalcones from the easily available starting materials 3-
hydroxypropionitrile derivatives and arylboronic acids is described. The procedure involves …

Cu-Catalyzed and iodine mediated synthesis of thioaurones via in situ C–S bond generation using xanthate as a sulfur surrogate

P Soundarya, G Sekar - Organic & Biomolecular Chemistry, 2022 - pubs.rsc.org
An efficient method for synthesizing thioaurones has been developed using xanthate as an
odorless sulfur surrogate. This reaction's key success lies in the use of iodine as a reagent …

Transition-Metal-free Michael Addition/Denitrative cyclization of 2′-Nitrochalcones and thioacetamides for the synthesis of thioflavanones

W Wang, Y Xu, X Liao, Z Yang, F Feng, X Wang… - Tetrahedron …, 2025 - Elsevier
A novel method for the preparation of thioflavanones from 2′-nitrochalcones and
thioacetamides has been developed. The reaction achieved the dissociation of inert groups …

DABCO Mediated Sulfur Activation‐Intramolecular De‐Nitration Strategy for the Synthesis of Novel Dihydrothiochromeno[4,3‐c]pyrazoles

Deepika, AK Paul, CC Malakar… - Asian Journal of …, 2023 - Wiley Online Library
A facile and highly efficient metal‐free approach has been unfolded for the synthesis of
novel dihydrothiochromeno [4, 3‐c] pyrazoles using elemental sulfur as a powerful …