Temperature-Dependent Oxidation of Hydroxylated Aldehydes by OH, SO4•–, and NO3 Radicals in the Atmospheric Aqueous Phase

M Mekic, T Schaefer, EH Hoffmann… - The Journal of …, 2023 - ACS Publications
T-dependent aqueous-phase rate constants were determined for the oxidation of the
hydroxy aldehydes, glyceraldehyde, glycolaldehyde, and lactaldehyde, by the hydroxyl …

Mild electrocatalytic hydrogenation of lactic acid to lactaldehyde and propylene glycol

TS Dalavoy, JE Jackson, GM Swain, DJ Miller, J Li… - Journal of …, 2007 - Elsevier
Reduction of fermentation-derived lactic acid (LA) offers a renewables-based pathway to
propylene glycol (PG), a large-scale commodity chemical, currently manufactured by the …

Thiamine Diphosphate Dependent KdcA‐Catalysed Formyl Elongation of Aldehydes

P Germer, E Gauchenova, L Walter, M Müller - ChemCatChem, 2019 - Wiley Online Library
The formose reaction, one of the oldest name reactions in organic chemistry, uses
formaldehyde as a C1 unit resulting in different monosaccharides and sugar‐like …

Electrochemistry for the Generation of Renewable Chemicals: One‐Pot Electrochemical Deoxygenation of Xylose to δ‐Valerolactone

OO James, W Sauter, U Schröder - ChemSusChem, 2017 - Wiley Online Library
In this study, the electrochemical conversion of xylose to δ‐valerolactone via carbonyl
intermediates is demonstrated. The conversion was achieved in aqueous media and at …

Thermodynamic and kinetic analysis of the dimerization of aqueous glyoxal

AR Fratzke, PJ Reilly - International journal of chemical kinetics, 1986 - Wiley Online Library
Equilibria and rates of interconversion between monomeric and dimeric glyoxal were
measured in aqueous solution. The equilibrium constant [G2]/[G1] 2 was 0.56 M− 1 at 25° C …

Accurate Computational Model for the Hydration Extent of Atmospherically Relevant Carbonyls on Aqueous Atmospheric Particles

MJ Elrod, JA Sedlak, H Ren - ACS Earth and Space Chemistry, 2021 - ACS Publications
The carbonyl hydration equilibria of several atmospherically relevant carbonyl compounds
were studied using nuclear magnetic resonance (NMR) spectroscopy and computationally …

The Role of a Methanol Dehydrogenase Modifier Protein and Aldehyde Dehydrogenase in the Growth of Pseudomonas AM1 on 1,2-Propanediol

M Steven Ford, P Dudley, C Anthony - Microbiology, 1985 - microbiologyresearch.org
Pure methanol dehydrogenase of Pseudomonas AMI oxidizes propanediol in a transitory
fashion when measured in a dye-linked assay with phenazine ethosulphate (PES) as …

Mechanistic Studies on RNA Strand Scission from a C2′-Radical

R Paul, MM Greenberg - The Journal of organic chemistry, 2016 - ACS Publications
The C2′-carbon–hydrogen bond in ribonucleotides is significantly weaker than other
carbohydrate carbon–hydrogen bonds in RNA or DNA. Independent generation of the C2 …

Reactions of Aldehydes and Ketones and their Derivatives

B Capon - Organic Reaction Mechanisms 1973 Reprint A: An …, 2008 - books.google.com
Two mechanisms are possible for the spontaneous hydrolysis of acetals derived from
salicylic acid: ¹ either there is an intramolecularly general-acid catalysed reaction of the un …

Effect of magnesium and lithium salts on the electroreduction of benzophenone in N, N-dimethylformamide as solvent

S Pellegrini, JC Folest, JY Nedelec… - Journal of electroanalytical …, 1989 - Elsevier
We have studied the effect of magnesium and lithium salts on the electroreduction of
benzophenone in DMF as solvent. Cyclic voltammetric studies and analysis of the products …