Photoinduced structural dynamics of molecular systems mapped by time-resolved X-ray methods

M Chergui, E Collet - Chemical reviews, 2017 - ACS Publications
We review the tremendous advances in ultrafast X-ray science, over the past 15 years,
making the best use of new ultrashort X-ray sources including table-top or large-scale …

Short-wavelength free-electron laser sources and science: a review

EA Seddon, JA Clarke, DJ Dunning… - Reports on Progress …, 2017 - iopscience.iop.org
This review is focused on free-electron lasers (FELs) in the hard to soft x-ray regime. The
aim is to provide newcomers to the area with insights into: the basic physics of FELs, the …

Roadmap of ultrafast x-ray atomic and molecular physics

L Young, K Ueda, M Gühr… - Journal of Physics B …, 2018 - iopscience.iop.org
X-ray free-electron lasers (XFELs) and table-top sources of x-rays based upon high
harmonic generation (HHG) have revolutionized the field of ultrafast x-ray atomic and …

Direct observation of coherent femtosecond solvent reorganization coupled to intramolecular electron transfer

E Biasin, ZW Fox, A Andersen, K Ledbetter, KS Kjær… - Nature …, 2021 - nature.com
It is well known that the solvent plays a critical role in ultrafast electron-transfer reactions.
However, solvent reorganization occurs on multiple length scales, and selectively …

Vibrational wavepacket dynamics in Fe carbene photosensitizer determined with femtosecond X-ray emission and scattering

K Kunnus, M Vacher, TCB Harlang, KS Kjær… - Nature …, 2020 - nature.com
The non-equilibrium dynamics of electrons and nuclei govern the function of photoactive
materials. Disentangling these dynamics remains a critical goal for understanding …

Finding intersections between electronic excited state potential energy surfaces with simultaneous ultrafast X-ray scattering and spectroscopy

KS Kjær, TB Van Driel, TCB Harlang, K Kunnus… - Chemical …, 2019 - pubs.rsc.org
Light-driven molecular reactions are dictated by the excited state potential energy
landscape, depending critically on the location of conical intersections and intersystem …

Revealing Excited‐State Trajectories on Potential Energy Surfaces with Atomic Resolution in Real Time

D Leshchev, A JS Valentine, P Kim… - Angewandte Chemie …, 2023 - Wiley Online Library
Photoexcited molecular trajectories on potential energy surfaces (PESs) prior to
thermalization are intimately connected to the photochemical reaction outcome. The excited …

Atomic-scale observation of solvent reorganization influencing photoinduced structural dynamics in a copper complex photosensitizer

T Katayama, TK Choi, D Khakhulin, AO Dohn… - Chemical …, 2023 - pubs.rsc.org
Photochemical reactions in solution are governed by a complex interplay between transient
intramolecular electronic and nuclear structural changes and accompanying solvent …

Mapping the emergence of molecular vibrations mediating bond formation

JG Kim, S Nozawa, H Kim, EH Choi, T Sato, TW Kim… - Nature, 2020 - nature.com
Fundamental studies of chemical reactions often consider the molecular dynamics along a
reaction coordinate using a calculated or suggested potential energy surface,,,–. But fully …

Capturing photochemical and photophysical transformations in iron complexes with ultrafast X-ray spectroscopy and scattering

KJ Gaffney - Chemical Science, 2021 - pubs.rsc.org
Light-driven chemical transformations provide a compelling approach to understanding
chemical reactivity with the potential to use this understanding to advance solar energy and …