Although carbon is the central element of organic chemistry, oxygen is the central element of
stereoelectronic control in organic chemistry. Generally, a molecule with a C–O bond has …

Understanding the interplay of multiple components (steric, electrostatic, stereoelectronic,
dispersive, etc.) that define the overall energy, structure, and reactivity of organic molecules …

Natural bond orbital (NBO) analysis is one of many available options for 'translating'
computational solutions of Schrödinger's wave equation into the familiar language of …

Stereoelectronic Effects illustrates the utility of stereoelectronic concepts using structure and
reactivity of organic molecules An advanced textbook that provides an up-to-date overview …

Acetals and ketals and their nitrogen and sulfur homologues are often considered to be
unconventional and potentially problematic scaffolding elements or pharmacophores for the …

Growing evidence indicates intermediacy of singlet dioxygen (1O2) in a variety of
pathophysiological processes. 1O2 has also found great utility of destructive actions for …

Organic systems still dominate several traditional areas of chemical science and well-known
applications, such as the synthesis of pharmaceutical compounds and drugs. However, a …

This review outlines the role of hyperconjugative interactions in the structure and reactivity of
organic molecules. After defining the common hyperconjugative patterns, we discuss the …

Stereoelectronic factors account for the apparent reversal of donor–acceptor properties of a
variety of functional groups by a simple change of their orientation in space. The new …

Stable tricyclic aminoperoxides can be selectively assembled via a catalyst-free three-
component condensation of β, δ′-triketones, H2O2, and an NH-group source such as …