Chiral sulfoxides: advances in asymmetric synthesis and problems with the accurate determination of the stereochemical outcome

J Han, VA Soloshonok, KD Klika, J Drabowicz… - Chemical Society …, 2018 - pubs.rsc.org
Chiral sulfoxides are in extremely high demand in nearly every sector of the chemical
industry concerned with the design and development of new synthetic reagents, drugs, and …

Self-disproportionation of enantiomers via achiral chromatography: a warning and an extra dimension in optical purifications

VA Soloshonok, C Roussel, O Kitagawa… - Chemical Society …, 2012 - pubs.rsc.org
This tutorial review describes the self-disproportionation of enantiomers (SDE) of chiral, non-
racemic compounds, subjected to chromatography on an achiral stationary phase using an …

NMR in operando monitoring of mechanochemically accelerated sublimations

F Puccetti, T Rinesch, S Suljić, K Rahimi, A Herrmann… - Chem, 2023 - cell.com
Solid-solid interactions in optically active materials lead to the phenomena of spontaneous
enantioenrichment, with implications in prebiotic chemistry and materials purification …

Self-disproportionation of enantiomers of chiral, non-racemic fluoroorganic compounds: role of fluorine as enabling element

AE Sorochinsky, JL Aceña, VA Soloshonok - Synthesis, 2013 - thieme-connect.com
This review discusses all available literature on the self-disproportionation of enantiomers
(SDE) of fluorine-containing compounds, resulting in a separation of racemic form from the …

Self-disproportionation of enantiomers via sublimation; new and truly green dimension in optical purification

J Han, DJ Nelson, AE Sorochinsky… - Current Organic …, 2011 - ingentaconnect.com
This Review article presents all available in the literature data on optical purification of
enantiomerically enriched organic compounds via simple procedure of sublimation. The …

Recent developments in optical resolution

R Siedlecka - Tetrahedron, 2013 - Elsevier
Resolution methods of racemic or enriched mixtures are continuously exploited and
developed, particularly to obtain both enantiomers of chiral compounds. This compilation …

Terminology related to the phenomenon 'self‐disproportionation of enantiomers'(SDE)

VA Soloshonok, KD Klika - Helvetica Chimica Acta, 2014 - Wiley Online Library
Terms related to the phenomenon self‐disproportion of enantiomers (SDE) are discussed,
particularly with respect to recently suggested alternative terms. Of the numerous terms …

An enantioselective synthesis of the key intermediate for triazole antifungal agents; application to the catalytic asymmetric synthesis of efinaconazole (Jublia)

K Tamura, N Kumagai, M Shibasaki - The Journal of Organic …, 2014 - ACS Publications
A new synthetic route, the shortest reported to date, to access a key intermediate for the
synthesis of various triazole antifungal agents was developed. The elusive tetrasubstituted …

Bioinspired Total Synthesis of Montanine‐Type Amaryllidaceae Alkaloids

X Bao, YX Cao, WD Chu, H Qu, JY Du… - Angewandte Chemie …, 2013 - Wiley Online Library
Inspiration from natural products biosynthesis for chemical synthesis has been playing an
increasingly crucial role in the discovery and invention of new synthetic strategies and …

Asymmetric Michael addition reaction organocatalyzed by stereoisomeric pyrrolidine sulfinamides under neat conditions. A brief study of self-disproportionation of …

G Reyes-Rangel, J Vargas-Caporali, E Juaristi - Tetrahedron, 2017 - Elsevier
This paper describes the synthesis of all four possible stereoisomers of the pyrrolidine
sulfinamides derived from (S)-proline or (R)-proline and either enantiomer of t …