Role of oxygen-bound reaction intermediates in selective electrochemical CO 2 reduction

X Zhi, A Vasileff, Y Zheng, Y Jiao… - Energy & Environmental …, 2021 - pubs.rsc.org
The electrochemical CO2 reduction reaction (CRR) is intrinsically complex given the
multiple possible reaction pathways and end products. Consequently, selectivity is a …

In situ characterization for boosting electrocatalytic carbon dioxide reduction

X Cao, D Tan, B Wulan, KS Hui, KN Hui… - Small …, 2021 - Wiley Online Library
The electrocatalytic reduction of carbon dioxide into organic fuels and feedstocks is a
fascinating method to implement the sustainable carbon cycle. Thus, a rational design of …

Electrochemical carbon monoxide reduction on polycrystalline copper: effects of potential, pressure, and pH on selectivity toward multicarbon and oxygenated …

L Wang, SA Nitopi, E Bertheussen, M Orazov… - Acs …, 2018 - ACS Publications
Understanding the surface reactivity of CO, which is a key intermediate during
electrochemical CO2 reduction, is crucial for the development of catalysts that selectively …

Atomistic Mechanisms Underlying Selectivities in C1 and C2 Products from Electrochemical Reduction of CO on Cu(111)

H Xiao, T Cheng, WA Goddard III - Journal of the American …, 2017 - ACS Publications
Practical environmental and energy applications of the electrochemical reduction of CO2 to
chemicals and fuels require far more efficient and selective electrocatalysts beyond the only …

Resolving local reaction environment toward an optimized CO 2-to-CO conversion performance

K Ye, G Zhang, XY Ma, C Deng, X Huang… - Energy & …, 2022 - pubs.rsc.org
The local reaction environment, especially the electrode–electrolyte interface and the
relevant hydrodynamic boundary layer in the vicinity of the cathode, plays a vital role in …

Advancements in electrochemical methanol synthesis from CO2: Mechanisms and catalyst developments

H Lee, N Park, TH Kong, S Kwon, S Shin, SG Cha… - Nano Energy, 2024 - Elsevier
Abstract Electrochemical CO 2 reduction (eCO 2 R) has emerged as a promising avenue,
offering the dual benefits of mitigating atmospheric CO 2 while generating value-added …

Bifunctional Alloys for the Electroreduction of CO 2 and CO

HA Hansen, C Shi, AC Lausche, AA Peterson… - Physical Chemistry …, 2016 - pubs.rsc.org
We use density functional theory to study the reduction of CO2 and CO to hydrocarbons
through a formyl pathway on (111) and (211) facets of L12 alloys with an A3B composition …

In-situ FTIR spectroscopic studies of electrocatalytic reactions and processes

JY Ye, YX Jiang, T Sheng, SG Sun - Nano Energy, 2016 - Elsevier
Investigation of electrocatalytic reactions and processes at molecule level is of essential
importance in the successful development of electrocatalyst. It is critical to understand the …

Surface reconstruction of pure-Cu single-crystal electrodes under CO-reduction potentials in alkaline solutions: A study by seriatim ECSTM-DEMS

YG Kim, A Javier, JH Baricuatro, D Torelli… - Journal of …, 2016 - Elsevier
Quasi-operando electrochemical scanning tunneling microscopy (ECSTM) recently showed
that a polycrystalline Cu electrode kept in 0.1 M KOH at− 0.9 V (SHE), a potential very close …

Recent progress of theoretical studies on electro-and photo-chemical conversion of CO 2 with single-atom catalysts

L Jiang, Q Yang, Z Xia, X Yu, M Zhao, Q Shi, Q Yu - RSC advances, 2023 - pubs.rsc.org
The CO2 reduction reaction (CO2RR) into chemical products is a promising and efficient
way to combat the global warming issue and greenhouse effect. The viability of the CO2RR …