Nanocrystal programmable assembly beyond hard spheres (or shapes) and other (simple) potentials

A Travesset - Current Opinion in Solid State and Materials Science, 2024 - Elsevier
Ligands are the key to almost any strategy in the assembly of programmable nanocrystals
(or nanoparticles) and must be accurately considered in any predictive model. Hard Spheres …

All-Perovskite Multicomponent Nanocrystal Superlattices

TV Sekh, I Cherniukh, E Kobiyama, TJ Sheehan… - ACS …, 2024 - ACS Publications
Nanocrystal superlattices (NC SLs) have long been sought as promising metamaterials, with
nanoscale-engineered properties arising from collective and synergistic effects among the …

High-Precision Calculation of Nanoparticle (Nanocrystal) Potentials of Mean Force and Internal Energies

A Upah, A Thomas, J Hallstrom… - Journal of Chemical …, 2023 - ACS Publications
Thermodynamic stability assessment of nanocrystal systems requires precise free energy
calculations. This study highlights the importance of meticulous control over various factors …

Predictive Modeling of Nanocrystal Orientation in Superlattices: Insights from Ligand Entropy

EK Price, WA Tisdale - Nano Letters, 2024 - ACS Publications
The self-assembly of nanocrystals (NCs) into close-packed, ordered superlattices (SLs) is of
broad, engineering interest. The coherent orientation of polyhedral nanocrystals within NC …

Patchy nanoparticles with surface complexity for directed self-assembly

T Vo - MRS Bulletin, 2024 - Springer
Patchy nanoparticles (PNPs) possess anisotropic surfaces that produce emergent
directionalities in interactions. Manipulation of such surface complexities offers a powerful …

Cooling‐Induced Order–Disorder Phase Transition in CsPbBr3 Nanocrystal Superlattices

U Filippi, S Toso, ML Zaffalon, A Pianetti, Z Li… - Advanced …, 2024 - Wiley Online Library
Perovskite nanocrystal superlattices are being actively studied after reports have emerged
on collective excitonic properties at cryogenic temperatures, where energetic disorder is …

Disorder and Halide Distributions in Cesium Lead Halide Nanocrystals as Seen by Colloidal 133Cs Nuclear Magnetic Resonance Spectroscopy

M Aebli, CJ Kaul, N Yazdani, F Krieg… - Chemistry of …, 2024 - ACS Publications
Colloidal nuclear magnetic resonance (cNMR) spectroscopy on inorganic cesium lead
halide nanocrystals (CsPbX3 NCs) is found to serve for noninvasive characterization and …

A multiscale approach to uncover the self-assembly of ligand-covered palladium nanocubes

X Chen, T Vo, P Clancy - Soft Matter, 2023 - pubs.rsc.org
Ligand-mediated superlattice assemblies of metallic nanocrystals represent a new type of
mesoscale materials whose structural ordering directly influence emergent collective …

Long live (d) CsPbBr 3 superlattices: colloidal atomic layer deposition for structural stability

V Lapointe, PB Green, AN Chen, R Buonsanti… - Chemical …, 2024 - pubs.rsc.org
Superlattice formation afforded by metal halide perovskite nanocrystals has been a
phenomenon of interest due to the high structural order induced in these self-assemblies, an …

Manganese-enriched CsPbCl 3 perovskite nanocrystals for self-assembled supercrystals

V Lapointe, MB Majewski - Chemical Communications, 2024 - pubs.rsc.org
The self-assembly of CsPbCl3 perovskite nanocrystals and their Mn2+-enriched analogs
into supercrystals is reported. Increasing Mn2+ content in the nanocrystals leads to …