Transition metal catalysis in confined spaces

SHAM Leenders, R Gramage-Doria… - Chemical Society …, 2015 - pubs.rsc.org
Transition metal catalysis plays an important role in both industry and in academia where
selectivity, activity and stability are crucial parameters to control. Next to changing the …

Supramolecular coordination: self-assembly of finite two-and three-dimensional ensembles

R Chakrabarty, PS Mukherjee, PJ Stang - Chemical reviews, 2011 - ACS Publications
Fascination with supramolecular chemistry over the past few decades has led to the
synthesis of an ever-increasing number of elegant and intricate functional structures with …

Giant hollow M n L 2n spherical complexes: structure, functionalisation and applications

K Harris, D Fujita, M Fujita - Chemical Communications, 2013 - pubs.rsc.org
Drawing inspiration from the self-assembly of hollow spherical virus capsids and protein
cages found in nature, a family of roughly spherical coordination polyhedra with general …

Enzyme mimics based upon supramolecular coordination chemistry

MJ Wiester, PA Ulmann… - Angewandte Chemie …, 2011 - Wiley Online Library
Recent advances in supramolecular coordination chemistry have allowed chemists to
synthesize macromolecular complexes that exhibit various properties intrinsic to enzymes …

Encapsulating semiconductor quantum dots in supramolecular cages enables ultrafast guest–host electron and vibrational energy transfer

S Lu, DJ Morrow, Z Li, C Guo, X Yu… - Journal of the …, 2023 - ACS Publications
In the field of supramolecular chemistry, host–guest systems have been extensively
explored to encapsulate a wide range of substrates, owing to emerging functionalities in …

Coordination/metal–organic cages inside out

T Tateishi, M Yoshimura, S Tokuda, F Matsuda… - Coordination Chemistry …, 2022 - Elsevier
Cage-like molecules, assembled by the coordination of multiple metal ions and organic
links, are pushing new frontiers in science due to their design flexibility and the resulting …

Pd (II) coordination sphere engineering: pyridine cages, quinoline bowls, and heteroleptic pills binding one or two fullerenes

B Chen, JJ Holstein, S Horiuchi, WG Hiller… - Journal of the …, 2019 - ACS Publications
Fullerenes and their derivatives are of tremendous technological relevance. Synthetic
access and application are still hampered by tedious purification protocols, peculiar …

Cucurbit [7] uril enables multi-stimuli-responsive release from the self-assembled hydrophobic phase of a metal organic polyhedron

SK Samanta, J Quigley, B Vinciguerra… - Journal of the …, 2017 - ACS Publications
Mixed self-assembly of ligands 1, 2, 1, 6-hexanediamine (HDA), and Pd (NO3) 2 afforded
Fujita-type metal organic polyhedron MOP1 (diameter≈ 8.2 nm), which is covalently …

Azobenzene‐Functionalized Metal–Organic Polyhedra for the Optically Responsive Capture and Release of Guest Molecules

J Park, LB Sun, YP Chen, Z Perry… - Angewandte …, 2014 - Wiley Online Library
Stimuli‐responsive metal–organic polyhedra (srMOPs) functionalized with azobenzene
showed UV‐irradiation‐induced isomerization from the insoluble trans‐srMOP to the soluble …

Self-assembled Pd (II) barrels as containers for transient merocyanine form and reverse thermochromism of spiropyran

P Howlader, B Mondal, PC Purba… - Journal of the …, 2018 - ACS Publications
Self-assembly of a cis-blocked Pd (II) 90° ditopic acceptor [cis-(tmeda) Pd (NO3) 2](M) with a
tetradentate donor L 1 [benzene-1, 4-di (4-terpyridine)] in 2: 1 molar ratio yielded two …