Near-infrared dyes for two-photon absorption in the short-wavelength infrared: strategies towards optical power limiting

S Pascal, S David, C Andraud, O Maury - Chemical Society Reviews, 2021 - pubs.rsc.org
This work provides an overview of the recent advances in the field of two-photon absorbing
chromophores active in the short-wavelength infrared (SWIR) spectral range. Herein the …

Chemistry of meso-Aryl-Substituted Expanded Porphyrins: Aromaticity and Molecular Twist

T Tanaka, A Osuka - Chemical reviews, 2017 - ACS Publications
Since the discovery of its facile synthesis in 2001, meso-aryl-substituted expanded
porphyrins have been developed as a new class of azaannulenes in light of their facile …

Synthesis of a Möbius carbon nanobelt

Y Segawa, T Watanabe, K Yamanoue, M Kuwayama… - Nature …, 2022 - nature.com
Technologies for the creation of topological carbon nanostructures have greatly advanced
synthetic organic chemistry and materials science. Although simple molecular nanocarbons …

Cycloparaphenylenes and related nanohoops

SE Lewis - Chemical Society Reviews, 2015 - pubs.rsc.org
The first synthesis of a cyclic oligophenylene possessing a radial π system was reported in
2008. In the short period that has elapsed since, there has been an ever-increasing level of …

Fluorescent Origin and Chiral Nature of MöBius Carbon Nanobelts

B Sun, X Ren, J Li, J Chen - The Journal of Physical Chemistry C, 2023 - ACS Publications
In this paper, we theoretically explore the physical mechanism of the fluorescent origin and
chiral nature of Möbius carbon nanobelts. The electron–hole recombination is promoted by …

Excited state aromaticity and antiaromaticity: opportunities for photophysical and photochemical rationalizations

M Rosenberg, C Dahlstrand, K Kilsa… - Chemical …, 2014 - ACS Publications
Aromaticity is one of the most widely applied concepts within chemistry. It plays a major role
in the rationalization of a range of chemical properties in the electronic ground state, despite …

Chemical topology: complex molecular knots, links, and entanglements

RS Forgan, JP Sauvage, JF Stoddart - Chemical Reviews, 2011 - ACS Publications
1.1. History and Background Knots and links are all around us (Figure 1). Be they functional
or decorative, we encounter them constantly, when, for example, tying simple bow knots in …

The supramolecular chemistry of strained carbon nanohoops

Y Xu, M von Delius - Angewandte Chemie International Edition, 2020 - Wiley Online Library
Since 1996, a growing number of strained macrocycles, comprising only sp2‐or sp‐
hybridized carbon atoms within the ring, have become synthetically accessible, with the [n] …

Photochemical reactions as key steps in organic synthesis

N Hoffmann - Chemical Reviews, 2008 - ACS Publications
Since the beginning of scientific chemistry, chemists have been interested in light as an
energy source to induce chemical reactions. 1 Absorbing light, molecules reach an …

Expanded porphyrins: intriguing structures, electronic properties, and reactivities

S Saito, A Osuka - Angewandte Chemie International Edition, 2011 - Wiley Online Library
The chemistry of expanded porphyrins, which are higher homologues of porphyrins, has
been intensively explored for the last three decades. Expanded porphyrins exhibit …