Polyhydrides of platinum group metals: Nonclassical interactions and σ-bond activation reactions
MA Esteruelas, AM Lopez, M Olivan - Chemical Reviews, 2016 - ACS Publications
The preparation, structure, dynamic behavior in solution, and reactivity of polyhydride
complexes of platinum group metals, described during the last three decades, are …
complexes of platinum group metals, described during the last three decades, are …
Metal–metal bonds: from fundamentals to applications
JF Berry, CC Lu - Inorganic chemistry, 2017 - ACS Publications
The year 2017 marks the 10th anniversary of the passing of Prof. F. Albert Cotton, who
described the first metal− metal multiple bonds in 1964. 1 Cotton's contributions to our …
described the first metal− metal multiple bonds in 1964. 1 Cotton's contributions to our …
Experimental and theoretical insights into the electronic properties of anionic N-heterocyclic dicarbenes through the rational synthesis of their transition metal …
AA Grineva, OA Filippov, Y Canac, JB Sortais… - Inorganic …, 2021 - ACS Publications
The lithiation of the NHC ligand backbone in Cp (CO) 2Mn (IMes) followed by
transmetalation on the C4 carbenic position with Cp (CO) 2FeI led to the heterobimetallic …
transmetalation on the C4 carbenic position with Cp (CO) 2FeI led to the heterobimetallic …
Investigations of tri-t-butyl tin hydride complexes of transition metals in small molecule activation and catalysis
Transition metal complexes containing the sterically encumbered SnBu t 3 group are the
focus of this brief review. The ability of tin compounds to modify both heterogeneous and …
focus of this brief review. The ability of tin compounds to modify both heterogeneous and …
Reversible Inter- and Intramolecular Carbon–Hydrogen Activation, Hydrogen Addition, and Catalysis by the Unsaturated Complex Pt(IPr)(SnBut3)(H)
The complex Pt (IPr)(SnBut3)(H)(1) was obtained from the reaction of Pt (COD) 2 with
But3SnH and IPr [IPr= N, N′-bis (2, 6-diisopropylphenyl) imidazol-2-ylidene]. Complex 1 …
But3SnH and IPr [IPr= N, N′-bis (2, 6-diisopropylphenyl) imidazol-2-ylidene]. Complex 1 …
Preparation of Heterobimetallic Ketimido-Actinide-Molybdenum Complexes
AJ Ayres, AJ Wooles, M Zegke, F Tuna… - Inorganic …, 2019 - ACS Publications
During our attempts to prepare paddlewheel actinide-molybdenum complexes of the type
[(X) An (MesNPR2) 3Mo (CO) 3](Mes= 2, 4, 6-trimethylphenyl; X= Cl or I; An= U or Th; R= iPr …
[(X) An (MesNPR2) 3Mo (CO) 3](Mes= 2, 4, 6-trimethylphenyl; X= Cl or I; An= U or Th; R= iPr …
A highly constrained cis-dihydride platinum complex trapped by cooperative gold/platinum dihydrogen activation
N Hidalgo, F De La Cruz-Martinez, MT Martín… - Chemical …, 2022 - pubs.rsc.org
A series of Au (I)/Pt (0) combinations that behave as bimetallic frustrated Lewis pairs
activates dihydrogen in a cooperative manner. The steric bulk of the terphenyl phosphines …
activates dihydrogen in a cooperative manner. The steric bulk of the terphenyl phosphines …
Syntheses and Structures of Ruthenium Complexes Containing a Ru‐H‐Tl Three‐Center–Two‐Electron Bond
W Bai, JX Zhang, T Fan, SKS Tse, W Shou… - Angewandte …, 2018 - Wiley Online Library
Abstract Treatment of CpRuH (PP)(PP= dppm, dppe) with TlPF6 produced [CpRu
(H)(Tl)(PP)] PF6. X‐ray diffraction and computational studies suggest that the complexes …
(H)(Tl)(PP)] PF6. X‐ray diffraction and computational studies suggest that the complexes …
1, 5-Cyclooctadienyl alcohols and ketones generate a new class of COD Pt complexes
AEE Wandler, MRM Koos, M Nieger, B Luy… - Dalton …, 2018 - pubs.rsc.org
1,5-Cyclooctadienyl alcohols and ketones generate a new class of COD Pt complexes - Dalton
Transactions (RSC Publishing) DOI:10.1039/C8DT00075A Royal Society of Chemistry View …
Transactions (RSC Publishing) DOI:10.1039/C8DT00075A Royal Society of Chemistry View …
Thermodynamic, Kinetic, Structural, and Computational Studies of the Ph3Sn–H, Ph3Sn–SnPh3, and Ph3Sn–Cr(CO)3C5Me5 Bond Dissociation Enthalpies
The kinetics of the reaction of Ph3SnH with excess• Cr (CO) 3C5Me5=• Cr, producing H Cr
and Ph3Sn–Cr, was studied in toluene solution under 2–3 atm CO pressure in the …
and Ph3Sn–Cr, was studied in toluene solution under 2–3 atm CO pressure in the …