Heterogeneous catalysts for CO 2 hydrogenation to formic acid/formate: from nanoscale to single atom

R Sun, Y Liao, ST Bai, M Zheng, C Zhou… - Energy & …, 2021 - pubs.rsc.org
Propelled by the vision of carbon-neutral energy systems, heterogeneous hydrogenation of
CO2 to formic acid/formate, a liquid hydrogen carrier, has been intensively studied as a …

Understanding the complexity in bridging thermal and electrocatalytic methanation of CO 2

H Kang, J Ma, S Perathoner, W Chu, G Centi… - Chemical Society …, 2023 - pubs.rsc.org
The selective methanation of CO2 is an important research area to meet the net-zero
emission targets. Furthermore, it is crucial to develop solutions to achieve carbon neutrality …

Methyl formate as a hydrogen energy carrier

R Sang, Z Wei, Y Hu, E Alberico, D Wei, X Tian… - Nature Catalysis, 2023 - nature.com
The use of renewable energy is central for the realization of a circular economy, which is
essential for further global economic development. In this background, hydrogen storage …

CO2 Hydrogenation on Cu/Al2O3: Role of the Metal/Support Interface in Driving Activity and Selectivity of a Bifunctional Catalyst

E Lam, JJ Corral‐Pérez, K Larmier… - Angewandte Chemie …, 2019 - Wiley Online Library
Selective hydrogenation of CO2 into methanol is a key sustainable technology, where
Cu/Al2O3 prepared by surface organometallic chemistry displays high activity towards CO2 …

Self-regeneration of supported transition metals by a high entropy-driven principle

S Hou, X Ma, Y Shu, J Bao, Q Zhang, M Chen… - Nature …, 2021 - nature.com
Abstract The sintering of Supported Transition Metal Catalysts (STMCs) is a core issue
during high temperature catalysis. Perovskite oxides as host matrix for STMCs are proven to …

Carbon Encapsulation of Supported Metallic Iridium Nanoparticles: An in Situ Transmission Electron Microscopy Study and Implications for Hydrogen Evolution …

P Liu, A Klyushin, P Chandramathy Surendran… - ACS …, 2023 - ACS Publications
Carbon-supported metal nanoparticles (NPs) comprise an important class of heterogeneous
catalysts. The interaction between the metal and carbon support influences the overall …

Deciphering Metal–Oxide and Metal–Metal Interplay via Surface Organometallic Chemistry: A Case Study with CO2 Hydrogenation to Methanol

SR Docherty, C Copéret - Journal of the American Chemical …, 2021 - ACS Publications
Processes that rely on heterogeneous catalysts underpin the production of bulk chemicals
and fuels. In spite of this, understanding of the interplay between the structure and reactivity …

Bifunctionality of Re Supported on TiO2 in Driving Methanol Formation in Low-Temperature CO2 Hydrogenation

N Phongprueksathat, KW Ting, S Mine, Y Jing… - ACS …, 2023 - ACS Publications
Low temperature and high pressure are thermodynamically more favorable conditions to
achieve high conversion and high methanol selectivity in CO2 hydrogenation. However, low …

Lewis Acid Strength of Interfacial Metal Sites Drives CH3OH Selectivity and Formation Rates on Cu‐Based CO2 Hydrogenation Catalysts

G Noh, E Lam, DT Bregante, J Meyet, P Šot… - Angewandte …, 2021 - Wiley Online Library
CH3OH formation rates in CO2 hydrogenation on Cu‐based catalysts sensitively depend on
the nature of the support and the presence of promoters. In this context, Cu nanoparticles …

Catalytic Hydrogenation of CO2 to Formate Using Ruthenium Nanoparticles Immobilized on Supported Ionic Liquid Phases

SJ Louis Anandaraj, L Kang, S DeBeer, A Bordet… - Small, 2023 - Wiley Online Library
Ruthenium nanoparticles (NPs) immobilized on imidazolium‐based supported ionic liquid
phases (Ru@ SILP) act as effective heterogeneous catalysts for the hydrogenation of carbon …