The replacement of one or more pyrrolic building block (s) of a porphyrin by a nonpyrrolic
heterocycle leads to the formation of so-called pyrrole-modified porphyrins (PMPs) …

The world of modified porphyrins changed forever when an N-confused porphyrin (NCP), a
porphyrin isomer, was first published in 1994. The replacement of one inner nitrogen with a …

Selective direct alkylation of indenes is important for the synthesis and decoration of indene
derivatives. In contrast to traditional alkylation methods, using unactivated alcohol as …

The unique environment within the core of carbaporphyrinoid systems provides a platform to
explore unusual organometallic chemistry. The ability of these structures to form stable …

The large expanded telluraporphyrin, tetratellura [36] octaphyrin (1.1. 1.1. 1.1. 1.1), was
synthesized in 7% yield by acid-catalyzed condensation of pyrrole with 2, 5-bis …

Various core-modified tellurophene-containing pentaphyrin (2.1. 1.1. 1) s were synthesized
via (3+ 2) condensation of 16-telluratripyrrane with different heterodiols under mild acid …

Core-modified porphyrins have been widely investigated and exhibit diverse characteristics.
Heteroporphyrins of this type retain the framework found in true porphyrins but have O, S …

Pyrazoloporphyrins (PzPs), which are porphyrin analogues incorporating a pyrazole
subunit, are examples of carbaporphyrin-type structures with a carbon atom within the …

BF 3• OEt 2, as a typical Lewis acid catalyst with excellent catalytic capacity, plays an
important role in many reactions, such as coupling, cyclization and rearrangement, and it is …

Ditelluraporphodimethene, a nonaromatic porphyrinoid containing two tellurophene rings,
reacted with palladium (II), platinum (II), and rhodium (I) following two different paths …