Herein we report the synthesis and characterization of anionic boron-and carbon-based
Kekulé diradicaloids spanned by ap-phenylene bridge. In contrast to Thiele's hydrocarbon, a …

Thiele's hydrocarbon occupies a central role as an open-shell platform for new organic
materials, however little is known about its redox behaviour. While recent synthetic …

Herein, we disclose cyclic (alkyl)(amino) carbenes (CAACs) to be one‐electron reductants
under the formation of a transient radical cation as indicated by EPR spectroscopy. The …

Herein, a new type of carbodicarbene (CDC) comprising two different classes of carbenes is
reported; NHC and CAAC as donor substituents and compare the molecular structure and …

Herein, we report nickel (0)-catalyzed cross-coupling reactions of NHC/CAAC-based
carbodicarbene (NHC= N-heterocyclic carbene and CAAC= cyclic (alkyl)(amino) carbene) …

Reduction of 2-H-substituted pyrrolinium cations via initially formed secondary radicals
results in either dimerisation or H-abstracted products, while the outcome depends on the N …

We demonstrate that 2‐alkenylarylaldimines and ketimines undergo thermal 6π‐
azaelectrocyclization to generate a wide range of azabicyclic o‐quinodimethanes (o …

Herein, we report the synthesis, characterization, and reactivity of α, α′-diamino-p-
tetrafluoroquinodimethane, ap-tetrafluorophenylene-bridged monosubstituted carbene …

Herein, we report diamidocarbene (DAC)-based Thiele and Tschitschibabin hydrocarbons,
diradicaloids that contain four carbonyl/amido functional groups. The impact of two different …

An extended class of organic multi‐redox systems was derived from bicyclic (alkyl) amino
carbenes (BICAACs). The highly‐conjugated system undergoes a total of 4 redox events …