Catalytic Upcycling of Polyolefins

J Sun, J Dong, L Gao, YQ Zhao, H Moon… - Chemical …, 2024 - ACS Publications
The large production volumes of commodity polyolefins (specifically, polyethylene,
polypropylene, polystyrene, and poly (vinyl chloride)), in conjunction with their low unit …

From plastic waste to treasure: selective upcycling through catalytic technologies

S Yue, P Wang, B Yu, T Zhang, Z Zhao… - Advanced Energy …, 2023 - Wiley Online Library
The huge amount of plastic wastes has become a pressing global environmental problem,
leading to severe environmental pollution and resource depletion through conventional …

Two mesoporous domains are better than one for catalytic deconstruction of polyolefins

A Tennakoon, X Wu, M Meirow, D Howell… - Journal of the …, 2023 - ACS Publications
Catalytic hydrogenolysis of polyolefins into valuable liquid, oil, or wax-like hydrocarbon
chains for second-life applications is typically accompanied by the hydrogen-wasting co …

Selective upcycling of polyolefins into high-value nitrogenated chemicals

B Zhao, Z Hu, Y Sun, R Hajiayi, T Wang… - Journal of the American …, 2024 - ACS Publications
The selective upcycling of polyolefins to create products of increased value has emerged as
an innovative approach to carbon resource stewardship, drawing significant scientific and …

SMSI-induced charge transfer for selective hydrogenolysis of polyolefins

W Tu, M Chu, X Wang, X Wang, Y Li, W Yang… - Applied Catalysis B …, 2023 - Elsevier
The in-depth mechanism of the emerging Ru-catalyzed polyolefin hydrogenolysis remains
unclear. Here, we overcome this challenge by constructing a strong metal-support …

A two-stage strategy for upcycling chlorine-contaminated plastic waste

PA Kots, BC Vance, CM Quinn, C Wang… - Nature …, 2023 - nature.com
Chemical upcycling of polyolefin plastic waste to lubricant, wax and fuel-range
hydrocarbons over metal-based catalysts is a crucial technological solution to the enormous …

Hydrogen-free catalytic depolymerization of waste polyolefins at mild temperatures

JN Hancock, JE Rorrer - Applied Catalysis B: Environmental, 2023 - Elsevier
Reductive methods of polyolefin waste deconstruction such as hydrogenolysis/
hydrocracking have enabled advances in plastic upcycling at low temperatures. However …

Investigation into the reaction pathways and catalyst deactivation for polyethylene hydrogenolysis over silica-supported cobalt catalysts

SS Borkar, R Helmer, S Panicker… - … Sustainable Chemistry & …, 2023 - ACS Publications
Chemical repurposing has emerged as a promising route to valorize “end-of-use” plastic
waste and mitigate its release to the environment. In this work, we applied silica-supported …

Unraveling the role of water in mechanism changes for economically viable catalytic plastic upcycling

T Kwon, B Ahn, KH Kang, W Won, I Ro - Nature Communications, 2024 - nature.com
The surge in global plastic production, reaching 400.3 million tons in 2022, has exacerbated
environmental pollution, with only 11% of plastic being recycled. Catalytic recycling …

Chemical upcycling of polyolefin plastics using structurally well-defined catalysts

S Sun, W Huang - JACS Au, 2024 - ACS Publications
Single-use polyolefins are widely used in our daily life and industrial production due to their
light weight, low cost, superior stability, and durability. However, the rapid accumulation of …