In recent years, visible light-induced transition metal catalysis has emerged as a new
paradigm in organic photocatalysis, which has led to the discovery of unprecedented …

The merger of photoredox catalysis with transition metal catalysis, termed
metallaphotoredox catalysis, has become a mainstay in synthetic methodology over the past …

Photocatalyzed and photosensitized chemical processes have seen growing interest
recently and have become among the most active areas of chemical research, notably due …

Asymmetric catalysis is a major theme of research in contemporary synthetic organic
chemistry. The discovery of general strategies for highly enantioselective photochemical …

Alkyl radicals are key intermediates in organic synthesis. Their classic generation from alkyl
halides has a severe drawback due to the employment of toxic tin hydrides to the point that …

The substitution of an alkyl electrophile by a nucleophile is a foundational reaction in
organic chemistry that enables the efficient and convergent synthesis of organic molecules …

BACKGROUND The recent resurgence and dramatic evolution of visible-light photoredox
catalysis has led to a paradigm shift in organic synthesis that encompasses activation of …

Enantioconvergent catalysis has expanded asymmetric synthesis to new methodologies
able to convert racemic compounds into a single enantiomer. This review covers recent …

The enantioconvergent cross-coupling of racemic alkyl halides represents a powerful tool for
the synthesis of enantioenriched molecules. In this regard, the first-row transition metal …

We describe a new catalytic strategy to transcend the energetic limitations of visible light by
electrochemically priming a photocatalyst prior to excitation. This new catalytic system is …