There are mechanistic dichotomies with regard to the formation, electronic structures and
reaction mechanisms of metal–oxygen intermediates, since these metal–oxygen species …

Metalloenzymes utilize inexpensive and earth-abundant transition metal ions as important
co-factors to enable binding of a dioxygen molecule so that it can be used in various …

The combination of Co (II) and peracetic acid (PAA) is a promising advanced oxidation
process for the abatement of refractory organic contaminants, and acetylperoxy (CH 3 CO …

Mononuclear metal–oxygen species, such as metal-superoxo,-peroxo,-hydroperoxo and-
oxo complexes, are key intermediates involved in dioxygen activation and oxidation …

In reactions of significance to alternative energy schemes, metal catalysts are needed to
overcome kinetically and thermodynamically difficult processes. Often, high-oxidation-state …

H2 and O2 evolutions occur simultaneously for conventional particulate photocatalytic
overall water splitting (PPOWS), leading to a significant backward reaction and the formation …

Redox-inactive metal ions play vital roles in biological O2 activation and oxidation reactions
of various substrates. Recently, we showed a distinct reactivity of a peroxocobalt (III) …

A mononuclear manganese( iii )–hydroperoxo complex: synthesis by activating dioxygen and
reactivity in electrophilic and nucleophilic reactions - Chemical Communications (RSC …

The introduction of a pyridine moiety into the skeleton of a polyazamacrocyclic ligand affects
both the thermodynamic properties and the coordination kinetics of the resulting metal …

Mononuclear nonheme iron (III)-hydroperoxo intermediates play key roles in biological
oxidation reactions. In the present study, we report the highly intriguing reactivity of a …