Alkyl borane-mediated metal-free ring-opening (co) polymerizations of oxygenated monomers

C Zhang, X Geng, X Zhang, Y Gnanou… - Progress in Polymer …, 2023 - Elsevier
Sensibility to environmental concerns and the actual demand for polymeric materials free of
any metal contaminants in most applications have directed research towards significant …

Sustainable conversion of carbon dioxide: an integrated review of catalysis and life cycle assessment

J Artz, TE Müller, K Thenert, J Kleinekorte… - Chemical …, 2018 - ACS Publications
CO2 conversion covers a wide range of possible application areas from fuels to bulk and
commodity chemicals and even to specialty products with biological activity such as …

Sulfur chemistry in polymer and materials science

H Mutlu, EB Ceper, X Li, J Yang… - Macromolecular …, 2019 - Wiley Online Library
Sulfur and its functional groups are major players in an area of exciting research taking
place in modern polymer and materials science, both in academia and industry. In fact …

Recent trends in catalytic polymerizations

DJ Walsh, MG Hyatt, SA Miller, D Guironnet - ACS Catalysis, 2019 - ACS Publications
Polymers have become one of the largest and most important materials we use in daily life.
Their popularity has stemmed from their wide range of material properties combined with …

Copolymerization of carbon dioxide and epoxides by metal coordination complexes

CM Kozak, K Ambrose, TS Anderson - Coordination Chemistry Reviews, 2018 - Elsevier
The catalytic copolymerization of CO 2 with epoxides to give polycarbonates was discovered
nearly 50 years ago. The last 10 years have been particularly exciting for the development …

Perfectly alternating and regioselective copolymerization of carbonyl sulfide and epoxides by metal‐free Lewis pairs

JL Yang, HL Wu, Y Li, XH Zhang… - Angewandte Chemie …, 2017 - Wiley Online Library
The preparation of perfectly alternating and regioslective copolymers derived from the
copolymerization of carbonyl sulfide (COS) and epoxides by metal‐free Lewis pair catalysts …

Carbon dioxide-based copolymers with various architectures

Y Li, YY Zhang, LF Hu, XH Zhang, BY Du… - Progress in Polymer …, 2018 - Elsevier
This review highlights recent advances in the synthesis of carbon dioxide (CO 2)-based
copolymers with both linear (di-, tri-, and multi-block, etc.) and non-linear (star-block and …

Poly (monothiocarbonate) s from the alternating and regioselective copolymerization of carbonyl sulfide with epoxides

M Luo, XH Zhang, DJ Darensbourg - Accounts of Chemical …, 2016 - ACS Publications
Conspectus Carbonyl sulfide (COS) is an air pollutant that causes acid rain, ozonosphere
damage, and carbon dioxide (CO2) generation. It is a heterocumulene and structural …

Precise synthesis of sulfur-containing polymers via cooperative dual organocatalysts with high activity

CJ Zhang, HL Wu, Y Li, JL Yang, XH Zhang - Nature communications, 2018 - nature.com
Metal-free and controlled synthesis of sulfur-containing polymer is still a big challenge in
polymer chemistry. Here, we report a metal-free, living copolymerization of carbonyl sulfide …

Making various degradable polymers from epoxides using a versatile dinuclear chromium catalyst

Y Liu, JZ Guo, HW Lu, HB Wang, XB Lu - Macromolecules, 2018 - ACS Publications
The environmental impact of industrially important plastics can be minimized by using
renewable feedstocks and preparing biodegradable polymers. A significantly more …