The synthesis of molecules that feature main-group elements in unusual oxidation states
and coordination environments is a primary pursuit of main-group chemistry. The p-block …

Since the seminal report on Mg in the+ I oxidation state in 2007, low-valent complexes
featuring a MgI–MgI bond developed from trophy molecules to state-of-the-art reducing …

The complex diberyllocene, CpBeBeCp (Cp, cyclopentadienyl anion), has been the subject
of numerous chemical investigations over the past five decades yet has eluded experimental …

The reactions of anionic aluminium or gallium nucleophiles {K [E (NON)]} 2 (E= Al, 1; Ga, 2;
NON= 4, 5-bis (2, 6-diisopropylanilido)-2, 7-di tert-butyl-9, 9-dimethylxanthene) with …

The synthesis of a series of isostructural organometallic complexes featuring Ae–Tr bonds
(Ae= Be, Mg; Tr= Al, Ga, In) has been investigated, and their electronic structures probed by …

Some scientists might consider group 2 chemistry as “boring, closed shell and all ionic,
aqueous chemistry, where everything is known! It is not worth investigating”. How wrong …

The presence of complex Schlenk equilibria is a central property of synthetically invaluable
Grignard reagents substantially affecting their reactivity and selectivity in chemical …

A Neutral Beryllium(I) Radical - Czernetzki - 2021 - Angewandte Chemie International Edition -
Wiley Online Library Skip to Article Content Skip to Article Information Wiley Online Library …

Beryllium has a unique combination of properties which has made it a vital component in a
wide range of technical sectors and consumer industries. However, beryllium is extremely …

This paper discusses the legislative response to handling beryllium and its compounds as
well as the administrative regulations resulting from their classification as potential human …