The large carbon footprint of the Haber–Bosch process, which provides ammonia for
fertilizers but also the feedstock for all nitrogenous commercial products, has fueled the …

The current status of homogeneous iron catalysis in organic chemistry is contemplated, as
are the reasons why this particular research area only recently starts challenging the …

High-oxidation-state 3d metal species have found a wide range of applications in modern
synthetic chemistry and materials science. They are also implicated as key reactive species …

The preparation and characterization of a series of magnesium (II) iodide complexes
incorporating β‐diketiminate ligands of varying steric bulk and denticity, namely,[(ArNCMe) …

The activation of abundant molecules such as hydrocarbons and atmospheric nitrogen (N2)
remains a challenge because these molecules are often inert. The formation of carbon …

The electronic structure, spectroscopic features, and (catalytic) reactivity of complexes with
nitrogen‐centered radical ligands are described. Complexes with aminyl ([M (. NR2)]) …

We present a family of trigonal pyramidal iron (II) complexes supported by tris (pyrrolyl-α-
methyl) amine ligands of the general formula [M (solv) n][(tpaR) Fe](M= Na, R= tert-butyl (1) …

“Nitrogen fixation”, the reduction of dinitrogen (N2) to two ammonia (NH3) molecules, by the
Mo-dependent nitrogenase is essential for all life. Despite four decades of research, a …

We describe herein the hydrogen-atom transfer (HAT)/proton-coupled electron-transfer
(PCET) reactivity for FeIV–oxo and FeIII–oxo complexes (1–4) that activate C–H, N–H, and O …

The olefin metathesis reaction is among the most widely applicable catalytic reactions for
carbon–carbon double bond formation. Currently, Mo–and Ru–carbene catalysts are the …