This review highlights key reactivities relying on C–C bond cleavages of cyclopropenes.
Metal-catalyzed and metal-free transformations are covered in reactions involving direct ring …

The divergent total syntheses of complex natural products from a common intermediate have
attracted enormous attention in the chemical community in the past few years because it can …

The factors controlling the reactivities and stereoselectivities in the Diels–Alder reactions of
substituted cyclopropenes with butadiene were explored with M06-2X density functional …

This short review focuses on the most relevant achievements in the field of cyclopropene
chemistry including their syntheses, reactivities, and applications. As the chemistry of …

UbiA prenyltransferases (PTs) play an important role in prenylation of aromatic compounds
with diverse bioactivities. The deep and comprehensive understanding of their substrate …

The first and asymmetric total synthesis of cyclocitrinol, an unusual C25 steroid, has been
accomplished in a linear sequence of 18 steps from commercially available compound 11 …

The following review article provides an overview of oxidopyrylium [5+ 2] cycloaddition
chemistry, with a particular emphasis placed on seminal historical developments and …

With the synergistic activation of alkynyl alcohols and alkynyl enones by a single gold
catalyst, diverse multisubstituted spirocyclopenta [c] furans were synthesized in good to …

We present a novel nickel-catalyzed reaction of indole-tethered 2-alkynylphenol esters with
various (hetero) aryl boronic acids, resulting in the synthesis of diversely functionalized …

Dynamic kinetic asymmetric transformation (DYKAT) reactions of racemic diastereomer
mixtures that afford the products as essentially single diastereomers with high …