This review serves to document advances in the synthesis, versatile bonding, and reactivity
of molecular main group metal hydrides within Groups 1, 2, and 12–16. Particular attention …

Heteroatom-centered diradical (oid) s have been in the focus of molecular main group
chemistry for nearly 30 years. During this time, the diradical concept has evolved and the …

Since the latter quarter of the twentieth century, main group chemistry has undergone
significant advances. Power's timely review in 2010 highlighted the inherent differences …

The focus of this review is the presentation of the most important aspects of chemical
bonding in molecules of the main group atoms according to the current state of knowledge …

Transition metals can assemble to form multinuclear complexes by engaging in direct metal-
to-metal interactions. Metal–metal covalent bonds provide a large perturbation in electronic …

This review is essentially an update of one entitled “π-Bonding and The Lone Pair Effect in
Multiple Bonds Between Heavier Main Group Elements” which was published more than 10 …

In recent decades, it has generally been recognized that carbenes play an important role as
transient intermediates. As a result of a number of stable carbenes having been isolated and …

The preparation and characterization of a series of magnesium (II) iodide complexes
incorporating β‐diketiminate ligands of varying steric bulk and denticity, namely,[(ArNCMe) …

This article highlights recent efforts of this laboratory in the stabilization of highly reactive,
low-oxidation-state, main-group molecules using bulky N-heterocyclic carbene ligands [L …

This Award Article targets the evolving, yet surprisingly fruitful, chemistry of N-heterocyclic
carbenes with low-oxidation-state main-group elements. Specifically, the chemistry of …