Thermal C–C bond cleavage reactions allow the construction of structurally diverse
molecular skeletons via predictable and efficient bond reorganizations. Visible light …

Rearrangement reactions, one of the most significant transformations in organic chemistry,
play an irreplaceable role in improving synthetic efficiency and molecular complexity …

The association of an electron-rich substrate with an electron-accepting molecule can
generate a new molecular aggregate in the ground state, called an electron donor–acceptor …

Radical aryl migrations are powerful techniques to forge new bonds in aromatic compounds.
The growing popularity of photoredox catalysis has led to an influx of novel strategies to …

Conspectus Alkenes are ubiquitous in natural products and are extensively used as
synthetic feedstocks in multiple fields including organic synthesis, medicinal chemistry, and …

Halogen bonding, the noncovalent interaction based on electrophilic halogen substituents,
features very interesting properties, as illustrated by numerous applications continuously …

Traditional metal-catalysed cross-couplings of alkyl halides for C (sp 3)–C (sp 2) bond
formation are often challenging to achieve. Processes where the alkyl halide is initially …

Photocatalytic carboxylation of alkenes with CO2 is a promising and sustainable strategy to
synthesize high value-added carboxylic acids. However, it is challenging and rarely …

In recent years, radical C–C bond cleavage reactions have been increasingly understood
and used to perform transformations that complement traditional ionic processes. However …

Triplet ketone sensitizers are of central importance within the realm of photochemical
transformations. Although the radical-type character of triplet excited states of diaryl ketones …