Chemistry of dark clouds: databases, networks, and models

M Agúndez, V Wakelam - Chemical Reviews, 2013 - ACS Publications
The introduction of chemistry into astronomy is relatively recent and can be dated back to
about half a century ago, when molecules were discovered in space. In the 1930s it was …

Quantum scattering calculations on chemical reactions

SC Althorpe, DC Clary - Annual review of physical chemistry, 2003 - annualreviews.org
▪ Abstract This review discusses recent quantum scattering calculations on bimolecular
chemical reactions in the gas phase. This theory provides detailed and accurate predictions …

High-dimensional ab initio potential energy surfaces for reaction dynamics calculations

JM Bowman, G Czako, B Fu - Physical Chemistry Chemical Physics, 2011 - pubs.rsc.org
There has been great progress in the development of potential energy surfaces (PESs) for
reaction dynamics that are fits to ab initio energies. The fitting techniques described here …

Rapid neutral–neutral reactions at low temperatures: a new network and first results for TMC‐1

IWM Smith, E Herbst, Q Chang - Monthly Notices of the Royal …, 2004 - academic.oup.com
There is now ample evidence from an assortment of experiments, especially those involving
the CRESU (Cinétique de Réaction en Ecoulement Supersonique Uniforme) technique, that …

Prevalence of non-aromatic carbonaceous molecules in the inner regions of circumstellar envelopes

L Martínez, G Santoro, P Merino, M Accolla… - Nature …, 2020 - nature.com
Evolved stars are foundries of chemical complexity, gas and dust that provide the building
blocks of planets and life, and dust nucleation first occurs in their photosphere. The …

Reactions at very low temperatures: gas kinetics at a new frontier

IWM Smith - Angewandte Chemie International Edition, 2006 - Wiley Online Library
A new era in chemical kinetics was heralded 20 years ago by the results reported by
Bertrand Rowe, then at the Laboratoire d AØrothermique in Meudon.[1] Using an apparatus …

[HTML][HTML] Growth of carbon chains in IRC+ 10216 mapped with ALMA

M Agúndez, J Cernicharo, G Quintana-Lacaci… - Astronomy & …, 2017 - aanda.org
Linear carbon chains are common in various types of astronomical molecular sources.
Possible formation mechanisms involve both bottom-up and top-down routes. We have …

The interstellar chemistry of C3H and C3H2 isomers

JC Loison, M Agúndez, V Wakelam… - Monthly Notices of …, 2017 - academic.oup.com
We report the detection of linear and cyclic isomers of C3H and C3H2 towards various
starless cores and review the corresponding chemical pathways involving neutral (C3H x …

Three milieux for interstellar chemistry: gas, dust, and ice

E Herbst - Physical Chemistry Chemical Physics, 2014 - pubs.rsc.org
The interdisciplinary science of astrochemistry is 45 years of age, if we pinpoint its origin to
have occurred when the first polyatomic molecules were detected in the interstellar gas …

Oxygen chemistry in the circumstellar envelope of the carbon-rich star IRC+ 10216

M Agúndez, J Cernicharo - The Astrophysical Journal, 2006 - iopscience.iop.org
In this paper we study the oxygen chemistry in the C-rich circumstellar shells of IRC+ 10216.
The recent discoveries of oxygen-bearing species (water, hydroxyl radical, and …