Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?

F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …

Power of infrared and raman spectroscopies to characterize metal-organic frameworks and investigate their interaction with guest molecules

KI Hadjiivanov, DA Panayotov, MY Mihaylov… - Chemical …, 2020 - ACS Publications
The variety of functionalities and porous structures inherent to metal-organic frameworks
(MOFs) together with the facile tunability of their properties makes these materials suitable …

Effect of benzoic acid and dopamine hydrochloride as a modulator in the water resistance of Universitetet i Oslo-67: adsorption performance and mechanism

X Zhang, S Ma, B Gao, F Bi, Q Liu, Q Zhao, J Xu… - Journal of Colloid and …, 2023 - Elsevier
The severe hazards on ecological environment and human body caused by volatile organic
compounds (VOCs) have attracted worldwide substantial attention. In this research, a series …

Solar Light Driven H2O2 Production and Selective Oxidations Using a Covalent Organic Framework Photocatalyst Prepared by a Multicomponent Reaction

P Das, J Roeser, A Thomas - Angewandte Chemie, 2023 - Wiley Online Library
A chemically stable 2D microporous COF (PMCR‐1) was synthesized via the
multicomponent Povarov reaction. PMCR‐1 exhibits a remarkable and long‐term stable …

Metal–organic framework-based catalysts with single metal sites

YS Wei, M Zhang, R Zou, Q Xu - Chemical Reviews, 2020 - ACS Publications
Metal–organic frameworks (MOFs) are a class of distinctive porous crystalline materials
constructed by metal ions/clusters and organic linkers. Owing to their structural diversity …

Self-sacrifice MOFs for heterogeneous catalysis: Synthesis mechanisms and future perspectives

A Ahmad, S Khan, S Tariq, R Luque, F Verpoort - Materials Today, 2022 - Elsevier
This review depicts the exposure of self-sacrifice MOF, their structure, synthesis as well as
potential application from a prodigious angle. We elaborated critically each of the self …

Coordinatively unsaturated metal sites (open metal sites) in metal–organic frameworks: design and applications

Ü Kökçam-Demir, A Goldman, L Esrafili… - Chemical Society …, 2020 - pubs.rsc.org
Metal–organic frameworks (MOFs) can contain open metal sites (OMS) or coordinatively
unsaturated sites (CUS) or open coordination sites (OCS) when vacant Lewis acid sites on …

State of the art and prospects in metal–organic framework (MOF)-based and MOF-derived nanocatalysis

Q Wang, D Astruc - Chemical reviews, 2019 - ACS Publications
Metal–organic framework (MOF) nanoparticles, also called porous coordination polymers,
are a major part of nanomaterials science, and their role in catalysis is becoming central …

Generating catalytic sites in UiO-66 through defect engineering

X Feng, HS Jena, C Krishnaraj, K Leus… - … Applied Materials & …, 2021 - ACS Publications
UiO-66 is regarded as an epitome of metal–organic frameworks (MOFs) because of its
stability. Defect engineering has been used as a toolbox to alter the performance of MOFs …

Using nature's blueprint to expand catalysis with Earth-abundant metals

RM Bullock, JG Chen, L Gagliardi, PJ Chirik, OK Farha… - Science, 2020 - science.org
BACKGROUND Catalysis has had a transformative impact on society, playing a crucial role
in the production of modern materials, medicines, fuels, and chemicals. Precious metals …