Chemical conversion pathways for carbohydrates

C Chatterjee, F Pong, A Sen - Green Chemistry, 2015 - pubs.rsc.org
Biomass has emerged as a potential alternative feedstock to dwindling fossil fuel reserves.
Starting in the 1990s, extensive research has been directed towards the synthesis of useful …

Converting carbohydrates to bulk chemicals and fine chemicals over heterogeneous catalysts

MJ Climent, A Corma, S Iborra - Green chemistry, 2011 - pubs.rsc.org
In this Critical Review, we discuss how carbohydrates can be transformed into a variety of
chemicals through heterogeneous catalysis. We focus particularly on oxidation, reduction …

Glycerol ether synthesis: A bench test for green chemistry concepts and technologies

M Sutter, ED Silva, N Duguet, Y Raoul, E Métay… - Chemical …, 2015 - ACS Publications
Naturally occurring, glycerol ethers are generally pure enantiomers, and batylic, chimylic,
and selachylic alcohols (Scheme 1) are the major ones which can be found in lipid …

New processes for the selective production of 1-octene

PWNM Van Leeuwen, ND Clément… - Coordination Chemistry …, 2011 - Elsevier
Linear α-olefins, especially 1-hexene and 1-octene, are key components for the production
of LLDPE and the demand for 1-hexene and 1-octene increased enormously in recent …

Industrially applied and relevant transformations of 1, 3-butadiene using homogeneous catalysts

J Yang, P Wang, H Neumann, R Jackstell… - Industrial Chemistry & …, 2023 - pubs.rsc.org
In recent decades, the use of 1, 3-butadiene as a comparably cheap and abundant raw
material for new applications has attracted more and more interest, specifically in the …

Catalytic etherification of glycerol with short chain alkyl alcohols in the presence of Lewis acids

F Liu, KDO Vigier, M Pera-Titus, Y Pouilloux… - Green …, 2013 - pubs.rsc.org
Here we report the homogeneously-catalyzed etherification of glycerol with short chain alkyl
alcohols. Among the large variety of Brønsted and Lewis acids tested, we show here that …

The Telomerization of 1, 3‐Dienes–A Reaction Grows Up

TA Faßbach, AJ Vorholt, W Leitner - ChemCatChem, 2019 - Wiley Online Library
Telomerization is a versatile tool for synthesizing unsaturated ethers, amines and other
molecules starting from 1, 3‐dienes and respective nucleophiles. The homogeneously …

Synthesis of long alkyl chain ethers through direct etherification of biomass-based alcohols with 1-octene over heterogeneous acid catalysts

AM Ruppert, AN Parvulescu, M Arias, PJC Hausoul… - Journal of catalysis, 2009 - Elsevier
Heterogeneous etherification of various biomass-based alcohols with 1-octene was
investigated as a direct route for the synthesis of long alkyl chain ethers. Several acid …

Palladium (II)–acetylacetonate complexes containing phosphine and diphosphine ligands and their catalytic activities in telomerization of 1, 3-dienes with …

DS Suslov, MV Bykov, MV Belova, PA Abramov… - Journal of …, 2014 - Elsevier
A series of novel [Pd (acac-O, O′)(PˆP)] BF 4 and known complexes [Pd (acac-O, O′)(PR
3) 2] BF 4 (PˆP= dppm (1), dppp (2), dppb (3), dppf (4); R= Ph (5), p-Tol (6), i-Pr (7); acac= 2 …

Carbohydrate-based amphiphiles: resource for bio-based surfactants

L Wang, Y Queneau - Green chemistry and chemical engineering, 2019 - udl.hal.science
Carbohydrates are a family of biomolecules, ubiquitous in Nature, based on a common
polyhydoxylated backbone though varying in size (from small molecules to …