Metal phosphonates incorporating metalloligands: assembly, structures and properties

SS Bao, MF Qin, LM Zheng - Chemical Communications, 2020 - pubs.rsc.org
Metal phosphonates are an important class of metal–organic hybrid materials that exhibit
versatile structures, intriguing functions and high water and thermal stability. Despite a large …

Molecular design of supramolecular polymers with chelated units and their application as functional materials

IE Uflyand, GI Dzhardimalieva - Journal of Coordination Chemistry, 2018 - Taylor & Francis
This article summarizes the basic concepts and synthetic strategies leading to various types
of supramolecular polymers with chelated units, including linear, branched, cross-linked …

The Impact of the Alkali Metal Ion on the Crystal Structure and (Mechano) luminescence of Terbium (III) Tetrakis (β‐diketonates)

YS Kudyakova, PA Slepukhin… - European Journal of …, 2020 - Wiley Online Library
The novel terbium (III) tetrakis (β‐diketonates) M [TbL4] with different alkali metal
counterions (Na, K, Cs) based on functionalized trifluoromethylated β‐diketonate are …

Hydrated metal ions as weak Brønsted acids show promoting effects on proton conduction

XL Huang, YQ Chen, GH Wen, SS Bao, LM Zheng - CrystEngComm, 2022 - pubs.rsc.org
It is well-known that hydrated metal ions can act as Brønsted acids, which tend to donate
protons increasing the acidic proton concentration in materials, as well as the proton …

New Copper Complexes with N, O-Donor Ligands Based on Pyrazole Moieties Supported by 3-Substituted Acetylacetone Scaffolds

J Del Gobbo, C Santini, A Dolmella, Z Li, M Caviglia… - Molecules, 2024 - mdpi.com
The new 3-monosubstituted acetylacetone ligands, 3-(phenyl (1 H-pyrazol-1-yl) methyl)
pentane-2, 4-dione (HLacPz) and 3-((3, 5-dimethyl-1 H-pyrazol-1-yl)(phenyl) methyl) …

Preparation of hierarchical trimetallic coordination polymer film as efficient electrocatalyst for oxygen evolution reaction

XJ Bai, YN Li, XM Yang, MY Zhang, L Shao… - Chemical …, 2019 - pubs.rsc.org
A hierarchical trimetallic coordination polymer film was prepared using a spray-assisted
interface synthetic strategy and in situ deposited onto Ni foam (denoted as Co0. 5Ni0. 3Fe0 …

Controlled synthesis of supramolecular architectures of homo-and heterometallic complexes by programmable self-assembly

J Tong, LM Jia, P Shang, SY Yu - Crystal Growth & Design, 2018 - ACS Publications
The reaction of ligand (H2L) named 3-(3, 5-dimethyl-1 H-pyrazol-4-yl) pentane-2, 4-dione
and Cu (NO3) 2 produces two types of supramolecular homometallic complexes well …

Hydrothermal generation, structural versatility and properties of metal (ii)-organic architectures driven by a pyridine-tricarboxylic acid

N Zhao, Y Li, JZ Gu, MV Kirillova, AM Kirillov - Dalton Transactions, 2019 - pubs.rsc.org
An aromatic tricarboxylic acid, 4-(6-carboxy-pyridin-3-yl)-isophthalic acid (H3cpia), was
applied as a building block for the hydrothermal syntheses of a new series of twelve metal …

Multifaceted properties of an engineered three-dimensional Zn (ii)–metal–organic coordination polymer: synthesis, crystal structure, efficient photocatalytic …

RA Khan, A AlFawaz, I Hasan, NA AlMuryyi… - New Journal of …, 2024 - pubs.rsc.org
Metal–organic frameworks and coordination polymers (MOFs/CPs) have emerged as a rare
category of multidimensional materials with applications in many fields, particularly as …

2D and 3D mixed M II/Cu II metal–organic frameworks (M= Ca and Sr) with N, N′-2, 6-pyridinebis (oxamate) and oxalate: preparation and magneto-structural study

TS Fernandes, WDC Melo, LHG Kalinke… - Dalton …, 2018 - pubs.rsc.org
Three heterobimetallic complexes of formula [Ca2Cu3 (mpyba) 2 (2-apyma)(H2O) 7]· 8.3
H2O (1),[Sr2Cu3 (mpyba) 2 (2-apyma)(H2O) 8]· 11.6 H2O (2) and [Sr4. 5Cu4 (mpyba) 4 …