Thin‐film solar cells exceeding 22% solar cell efficiency: An overview on CdTe-, Cu (In, Ga) Se2-, and perovskite-based materials

M Powalla, S Paetel, E Ahlswede, R Wuerz… - Applied Physics …, 2018 - pubs.aip.org
Already, several technologies of polycrystalline thin‐film photovoltaic materials have
achieved certified record small‐cell power conversion efficiencies exceeding 22%. They are …

[HTML][HTML] Advances in CIGS thin film solar cells with emphasis on the alkali element post-deposition treatment

C Zhao, S Yu, W Tang, X Yuan, H Zhou, T Qi… - Materials Reports …, 2023 - Elsevier
In the past tens of years, the power conversion efficiency of Cu (In, Ga) Se 2 (CIGS) has
continuously improved and been one of the fastest growing photovoltaic technologies that …

Heavy Alkali Treatment of Cu(In,Ga)Se2 Solar Cells: Surface versus Bulk Effects

S Siebentritt, E Avancini, M Bär… - Advanced Energy …, 2020 - Wiley Online Library
Chalcopyrite solar cells achieve efficiencies above 23%. The latest improvements are due to
post‐deposition treatments (PDT) with heavy alkalis. This study provides a comprehensive …

Direct evidence for grain boundary passivation in Cu(In,Ga)Se2 solar cells through alkali-fluoride post-deposition treatments

N Nicoara, R Manaligod, P Jackson, D Hariskos… - Nature …, 2019 - nature.com
The properties and performance of polycrystalline materials depend critically on the
properties of their grain boundaries. Polycrystalline photovoltaic materials–eg hybrid halide …

Elucidating the mechanism of an RbF post deposition treatment in CIGS thin film solar cells

T Kodalle, MD Heinemann, D Greiner, HA Yetkin… - Solar …, 2018 - Wiley Online Library
The impact of a rubidium fluoride post deposition treatment (RbF‐PDT) on the material and
device properties of Cu (In, Ga) Se2 (CIGS) thin films and corresponding solar cells is …

Review of grain interior, grain boundary, and interface effects of K in CIGS solar cells: Mechanisms for performance enhancement

CP Muzzillo - Solar Energy Materials and Solar Cells, 2017 - Elsevier
Abstract Introducing K into Cu (In, Ga)(Se, S) 2 (CIGS) absorbers has led to recent world
record power conversion efficiencies for thin film polycrystalline solar cells. In this work, the …

Potassium doping for grain boundary passivation and defect suppression enables highly-efficient kesterite solar cells

Y Li, Z Wang, Y Zhao, D Luo, X Zhang, J Zhao… - Chinese Chemical …, 2024 - Elsevier
The complicated and diverse deep defects, voids, and grain boundary in the CZTSSe
absorber are the main reasons for carrier recombination and efficiency degradation. The …

[HTML][HTML] Alkali-induced grain boundary reconstruction on Cu (In, Ga) Se2 thin film solar cells using cesium fluoride post deposition treatment

TY Lin, I Khatri, J Matsuura, K Shudo, WC Huang… - Nano Energy, 2020 - Elsevier
Heavy alkali metal treatment is a key factor to approach high efficiency in Cu (In, Ga) Se 2
(CIGS) solar cells. Here, we show that the Cs-induced surface modification on CIGS thin-film …

Impact of a RbF Postdeposition Treatment on the Electronic Structure of the CdS/Cu(In,Ga)Se2 Heterojunction in High-Efficiency Thin-Film Solar Cells

D Hauschild, D Kreikemeyer-Lorenzo… - ACS Energy …, 2017 - ACS Publications
Recently, a world-record efficiency of 22.6% was achieved by applying a RbF
postdeposition treatment (PDT) on a Cu (In, Ga) Se2 (CIGSe) thin-film solar cell absorber …

Silver‐Alloyed Low‐Bandgap CuInSe2 Solar Cells for Tandem Applications

M Krause, SC Yang, S Moser, S Nishiwaki… - Solar …, 2023 - Wiley Online Library
Photovoltaic conversion efficiency of CuInSe2 solar cells is limited by low fill factor (FF) and
open‐circuit‐voltage (V OC) values compared to Si or perovskite solar cells. Herein, small …