Metal–organic framework (MOF)-, covalent-organic framework (COF)-, and porous-organic polymers (POP)-catalyzed selective C–H bond activation and …

S Daliran, AR Oveisi, Y Peng… - Chemical Society …, 2022 - pubs.rsc.org
Although C–H functionalization is one of the simplest reactions, it requires the use of highly
active and selective catalysts. Recently, C–H-active transformations using porous materials …

Advances in the E → Z Isomerization of Alkenes Using Small Molecule Photocatalysts

T Nevesely, M Wienhold, JJ Molloy, R Gilmour - Chemical reviews, 2021 - ACS Publications
Geometrical E→ Z alkene isomerization is intimately entwined in the historical fabric of
organic photochemistry and is enjoying a renaissance (Roth et al. Angew. Chem., Int. Ed …

Challenges and recent advancements in the transformation of CO 2 into carboxylic acids: straightforward assembly with homogeneous 3d metals

R Cauwenbergh, V Goyal, R Maiti, K Natte… - Chemical Society …, 2022 - pubs.rsc.org
The transformation of carbon dioxide (CO2) into useful chemicals, advanced materials, and
energy is a long-standing challenge in both fundamental science and industry. In recent …

Machine learning may sometimes simply capture literature popularity trends: a case study of heterocyclic Suzuki–Miyaura coupling

W Beker, R Roszak, A Wołos, NH Angello… - Journal of the …, 2022 - ACS Publications
Applications of machine learning (ML) to synthetic chemistry rely on the assumption that
large numbers of literature-reported examples should enable construction of accurate and …

Excited-state intramolecular proton-transfer (ESIPT) based fluorescence sensors and imaging agents

AC Sedgwick, L Wu, HH Han, SD Bull, XP He… - Chemical Society …, 2018 - pubs.rsc.org
In this review we will explore recent advances in the design and application of excited-state
intramolecular proton-transfer (ESIPT) based fluorescent probes. Fluorescence based …

Mechanistic aspects of the palladium‐catalyzed Suzuki‐Miyaura cross‐coupling reaction

MC D'Alterio, È Casals‐Cruañas… - … A European Journal, 2021 - Wiley Online Library
The story of C− C bond formation includes several reactions, and surely Suzuki‐Miyaura is
among the most outstanding ones. Herein, a brief historical overview of insights regarding …

Tackling solubility issues in organic synthesis: solid-state cross-coupling of insoluble aryl halides

T Seo - Palladium-Catalyzed Mechanochemical Cross …, 2024 - Springer
Conventional organic synthesis generally relies on the use of liquid organic solvents to
dissolve the reactants. Therefore, reactions of sparingly soluble or insoluble substrates are …

Automated iterative Csp3–C bond formation

DJ Blair, S Chitti, M Trobe, DM Kostyra, HMS Haley… - Nature, 2022 - nature.com
Fully automated synthetic chemistry would substantially change the field by providing broad
on-demand access to small molecules. However, the reactions that can be run …

Catalytic enantioselective functionalizations of C–H bonds by chiral iridium complexes

Ł Woźniak, JF Tan, QH Nguyen… - Chemical …, 2020 - ACS Publications
The development of catalytic enantioselective transformations, enabling the construction of
complex molecular scaffolds from simple precursors, has been a long-standing challenge in …

The Suzuki-Miyaura reaction after the Nobel prize

IP Beletskaya, F Alonso, V Tyurin - Coordination Chemistry Reviews, 2019 - Elsevier
Synthetic organic chemistry experienced a significant advance in the last quarter of the 20th
century with the advent of the transition-metal catalyzed cross-coupling reactions. The utility …