[HTML][HTML] Oxalato as polyatomic coordination center and magnetic coupler in copper (II)-polypyrazole inverse polynuclear complexes and coordination polymers

I Castro, ML Calatayud, M Orts-Arroyo, N Marino… - Coordination Chemistry …, 2022 - Elsevier
The present review provides an overview on inverse coordination chemistry and
magnetochemistry of copper (II) systems with oxalato as polyatomic coordination center and …

Inverse coordination metal complexes with oxalate and sulfur, selenium and nitrogen analogues as coordination centers. Topology and systematization

I Haiduc - Journal of Coordination Chemistry, 2020 - Taylor & Francis
The review is part of a series of articles which introduce the emerging concept of inverse
coordination. The article presents a panorama of inverse coordination complexes (ie metal …

Binuclear and tetranuclear Mn (II) clusters in coordination polymers derived from semirigid tetracarboxylate and N‑donor ligands: syntheses, new topology structures …

XL Li, GZ Liu, LY Xin, LY Wang - Journal of Solid State Chemistry, 2017 - Elsevier
Two topologically new Mn (II) coordination polymers, namely {[Mn 2 (H 4 ipca)(4, 4′-bpy)
1.5 (CH 3 CH 2 OH) 0.5 (H 2 O) 1.5]· 0.5 CH 3 CH 2 OH· 2.5 H 2 O} n (1) and {Mn 4 (H 4 …

Oxalate-based [Cu II Cr III] coordination compounds affected by the tridentate ligand, simple anion, and reactant ratio: structural and magnetic features

L Molčanov, P Šenjug, D Barišić, D Pajić… - Dalton …, 2022 - pubs.rsc.org
Seven novel oxalate-based [CuIICrIII] compounds:[Cu4 (terpy) 4Cl5][Cr (C2O4) 3]· 9H2O (1;
terpy= 2, 2′: 6′, 2′′-terpyridine),{[Cr2Cu4 (H2O) 2 (terpy) 4 (C2O4) 7]· 10H2O} n …

Cu (II) coordination polymers constructed by tetrafluoroterephthalic acid and varied imidazole-containing ligands: Syntheses, structures and properties

K Liu, Y Sun, L Deng, F Cao, J Han, L Wang - Journal of Solid State …, 2018 - Elsevier
Six new copper (II) coordination polymers combining 2, 3, 5, 6-tetrafluoroterephthalatic acid
(H 2 tfBDC) and diverse imidazole-containing ligands,{[Cu (tfBDC)(1, 2-bix) 2]· 2 (H 2 O)} n …

The influence of metal centres on the exchange interaction in heterometallic complexes with oxalate-bridged cations

LA Dubraja, M Jurić, F Torić, D Pajić - Dalton transactions, 2017 - pubs.rsc.org
The reaction of bis (phenanthroline) metal (II) cations (M= Mn2+, Co2+, Ni2+, Cu2+ and
Zn2+) with bis (oxalato) chromium (III) anions in a water/ethanol solution gives rise to a …

Binuclear copper complex as a new dual‐use catalyst for cycloaddition and coupling reactions: Synthesis, characterization, and application

M Amini, A Sheykhi, AA Khandar… - Applied Organometallic …, 2024 - Wiley Online Library
A binuclear copper (II) complex [Cu2 (dien) 2 (ox)(ClO4)](dien= diethylenetriamine and ox=
oxalate) was readily synthesized and obtained in the perchlorate salt form. The structure of …

1, 2, 4-triazole schiff base directed synthesis of polynuclear iron complexes: Investigating the magnetic properties going from a dimer to a 1D chain to a 3D framework

AM Li, E Rentschler - Polyhedron, 2018 - Elsevier
Based on two functionalized Schiff base ligands 4-(1H-imidazol-5-ylmethylene-amino)-4H-1,
2, 4-triazole (imztrz) and 4-(p-tolylidene-amino)-4H-1, 2, 4-triazole (toltrz), a series of three …

An oxalate-bridged copper (II) complex combining monodentate benzoate, 2, 2′-bipyridine and aqua ligands: Synthesis, crystal structure and investigation of …

FS Santana, M Briganti, RAA Cassaro, F Totti… - Molecules, 2020 - mdpi.com
A dinuclear copper (II) complex of formula [{Cu (bipy)(bzt)(OH2)} 2 (μ-ox)](1)(where bipy= 2,
2′-bipyridine, bzt= benzoate and ox= oxalate) was synthesised and characterised by …

Ladder-like [CrCu] coordination polymers containing unique bridging modes of [Cr (C 2 O 4) 3] 3− and Cr 2 O 7 2−

L Kanižaj, K Molčanov, F Torić, D Pajić, I Lončarić… - Dalton …, 2019 - pubs.rsc.org
Three heterometallic one-dimensional (1D) coordination polymers {A [CrCu2 (bpy) 2 (C2O4)
4]· H2O} n [A= K+ (1) and NH4+ (2); bpy= 2, 2′-bipyridine] and [(Cr2O7) Cu2 (C2O4)(phen) …