Construction of fused heterocycles by metal-mediated [2+ 2+ 2] cyclotrimerization of alkynes and/or nitriles

MR Shaaban, R El-Sayed, AHM Elwahy - Tetrahedron, 2011 - Elsevier
Heterocycles constitute one of the most interesting divisions of organic chemistry. A majority
of the compounds produced by nature as well as significant numbers of compounds …

Cobalt Catalysts for [2+2+2] Cycloaddition Reactions: Isolated Precatalysts and in situ Generated Catalysts

T Gläsel, BN Baumann, M Hapke - The Chemical Record, 2021 - Wiley Online Library
Abstract [2+ 2+ 2] Cycloaddition reactions belong to the not even large class of reactions,
which can be catalyzed or mediated by a significant number of different transition metals …

Beyond Reppe: building substituted arenes by [2+ 2+ 2] cycloadditions of alkynes

BR Galan, T Rovis - Angewandte Chemie International Edition, 2009 - Wiley Online Library
Synthetic sequel: The transition‐metal‐catalyzed [2+ 2+ 2] cycloaddition is an established
method for the construction of carbocyclic frameworks but is often plagued by poor …

Air‐Stable {(C5H5)Co} Catalysts for [2+2+2] Cycloadditions

A Geny, N Agenet, L Iannazzo… - Angewandte Chemie …, 2009 - Wiley Online Library
Cobalt cyclopentadienyl complexes incorporating a fumarate and a CO ligand (see picture)
efficiently catalyze inter‐and intramolecular [2+ 2+ 2] cycloadditions of alkynes, nitriles …

[PDF][PDF] Rhodium-catalyzed [2+ 2+ 2] cycloaddition for the synthesis of substituted pyridines, pyridones, and thiopyranimines

K Tanaka - Heterocycles, 2012 - triggered.edina.clockss.org
The transition-metal-catalyzed [2+ 2+ 2] cycloaddition of alkynes with nitriles is a useful and
atom-economical method for the synthesis of substituted pyridines. The use of isocyanates …

Cobalt-catalysed carbon-carbon bond-formation reactions

W Hess, J Treutwein, G Hilt - Synthesis, 2008 - thieme-connect.com
The recent developments in cobalt catalysis are compiled in this review covering the years
2000 through 2007. Special focus is directed towards cobalt-catalysed ring-formation …

Aromatic hydrocarbons as ligands. Recent advances in the synthesis, the reactivity and the applications of bis (η6-arene) complexes

G Pampaloni - Coordination Chemistry Reviews, 2010 - Elsevier
Synthetic procedures for bis (η6-arene) metal derivatives and aspects of their reactivity are
reviewed. Attention is focused on early transition metals (Groups 4–6) but, when necessary …

On-Demand Generation of an Efficient Catalyst for Pyridine Formation from Unactivated Nitriles and α,ω-Diynes Using CoCl2-6H2O, dppe, and Zn

K Kase, A Goswami, K Ohtaki, E Tanabe, N Saino… - Organic …, 2007 - ACS Publications
A highly practical, general method for catalytic formation of substituted pyridines from a
variety of unactivated nitriles and α, ω-diynes is given. The reactions which were catalyzed …

Cycloaddition of alkynes: Atom-economic protocols for constructing six-membered cycles

R Hua, M Victoria A. Abrenica… - Current Organic …, 2011 - benthamdirect.com
Recent advances on the synthesis of six-membered carbo-and heterocyclic compounds
including functionalized benzenes, 1, 3-cyclohexadienes, pyridines, pyridones, pyranones …

Homobimetallic rhodium NHC complexes as versatile catalysts for hydrosilylation of a multitude of substrates in the presence of ambient air

AJ Huckaba, TK Hollis, SW Reilly - Organometallics, 2013 - ACS Publications
Two recently reported air-and water-stable di-Rh complexes based on 1, 3-bis (3′-
butylbenzimidazol-2′-ylidene) benzene were utilized as catalysts for hydrosilylation …