Rare earth starting materials and methodologies for synthetic chemistry
F Ortu - Chemical Reviews, 2022 - ACS Publications
The number of rare earth (RE) starting materials used in synthesis is staggering, ranging
from simple binary metal-halide salts to borohydrides and “designer reagents” such as alkyl …
from simple binary metal-halide salts to borohydrides and “designer reagents” such as alkyl …
Magnetic and dielectric property control in the multivalent nanoscale perovskite Eu 0.5 Ba 0.5 TiO 3
We report nanoscale Eu0. 5Ba0. 5TiO3, a multiferroic in the bulk and candidate in the
search to quantify the electric dipole moment of the electron. Eu0. 5Ba0. 5TiO3, in the form of …
search to quantify the electric dipole moment of the electron. Eu0. 5Ba0. 5TiO3, in the form of …
Hexafluoroisopropoxides of divalent and trivalent lanthanides. Structures and luminescence properties
DM Kuzyaev, RV Rumyantsev, GK Fukin… - Russian Chemical …, 2014 - Springer
The reactions of amides Ln [N (SiMe 3) 2] 3 with hexafluoroisopropanol (CF 3) 2 CHOH
gave the corresponding alkoxides Ln [OCH (CF 3) 2] 3 (Ln= Ce (1), Gd (2), Tm (3)). The X …
gave the corresponding alkoxides Ln [OCH (CF 3) 2] 3 (Ln= Ce (1), Gd (2), Tm (3)). The X …
Gas-phase reactions of lanthanide cations with alcohols
JM Carretas, J Marçalo, AP de Matos - International Journal of Mass …, 2004 - Elsevier
The gas-phase reactions of the lanthanide series cations Ln+ (Ln= La–Lu, except Pm) with
methanol, ethanol, and 2-propanol were studied by Fourier transform ion cyclotron …
methanol, ethanol, and 2-propanol were studied by Fourier transform ion cyclotron …
The utility of N-methylimidazole and acetonitrile as solvents for the direct reaction of europium with alcohols including the first example of acetonitrile as a Á-η 1: η 1 …
WJ Evans, MA Greci, JW Ziller - Chemical Communications, 1998 - pubs.rsc.org
N-Methylimidazole and acetonitrile are suitable solvents for the direct reactions of europium
metal with 2, 6-Me2C6H3OH and 2, 6-Pri2C6H3OH, which lead to crystallographically …
metal with 2, 6-Me2C6H3OH and 2, 6-Pri2C6H3OH, which lead to crystallographically …
Synthesis and characterization of polynuclear lanthanide aryloxides
The reactions of europium and ytterbium in liquid ammonia with a solution of 1-naphthol in
tetrahydrofuran provide a convenient route to lanthanide aryloxides. The polymetallic …
tetrahydrofuran provide a convenient route to lanthanide aryloxides. The polymetallic …
Europium (II) and ytterbium (II) aryloxide chemistry: synthesis and crystal structure of [Eu (OC6H3But2-2, 6) 2 (THF) 3]· 0.75 C7H8 and [Yb (OC6H3But2-2, 6) 2 (NCMe) …
The reactions of europium and ytterbium with 2, 6-di-tert-butylphenol were studied by the
metal vapour synthesis technique and by dissolution in liquid ammonia. The lanthanide …
metal vapour synthesis technique and by dissolution in liquid ammonia. The lanthanide …
[PDF][PDF] 湿化学法制备纳米氧化镱的研究
赵玉宝， 黄传敬， 陈陆千， 翁维正， 万惠霖 - 2004 - core.ac.uk
摘要采用通常的溶液沉淀, 微乳液及均匀沉淀等溶液方法制备纳米氧化镱. TEM 观测显示,
采用H2O2 的溶液沉淀法和采用CTAB 的均匀沉淀法, 都可得到有较好分散, 尺度约为10 nm …
采用H2O2 的溶液沉淀法和采用CTAB 的均匀沉淀法, 都可得到有较好分散, 尺度约为10 nm …
Гексафторизопропоксиды двух-и трехвалентных лантаноидов. Строение и люминесцентные свойства
ДМ Кузяев, РВ Румянцев, ГК Фукин… - Известия Академии наук …, 2014 - elibrary.ru
Реакциями амидов Ln [N (SiMe3) 2] 3 с гексафторизопропанолом (CF3) 2CHOH
получены соответствующие алкоголяты Ln [OCH (CF3) 2] 3 (Ln= Ce (1), Gd (2), Tm (3)) …
получены соответствующие алкоголяты Ln [OCH (CF3) 2] 3 (Ln= Ce (1), Gd (2), Tm (3)) …
Synthesis and energetics of Na, K, Rb and Cs salts by reaction with 1, 2-ethanediol and 1, 4-butanediol
LMC Silva, PG Rosado, JB Branco, MA Antunes… - The Journal of Chemical …, 2017 - Elsevier
The study of direct reactions of Na, K, Rb and Cs with 1, 2-ethanediol and with 1, 4-
butanediol was undertaken as well as the reactions of Na and K with 1, 2-ethanediol by an …
butanediol was undertaken as well as the reactions of Na and K with 1, 2-ethanediol by an …