Since the first report of their isolation in 2007, magnesium (i) dimers have transitioned from
being chemical curiosities to versatile reducing agents that are used by an ever-increasing …

This review surveys the synthesis and reactivity of low-oxidation state metalate anions of the
d-block elements, with an emphasis on contributions reported between 2006 and 2022 …

Synthetic routes to lithium, magnesium, and zinc aluminyl complexes are reported, allowing
for the first structural characterization of an unsupported lithium–aluminium bond …

A Neutral Beryllium(I) Radical - Czernetzki - 2021 - Angewandte Chemie International Edition -
Wiley Online Library Skip to Article Content Skip to Article Information Wiley Online Library …

Through a combined experimental and computational (DFT) approach, the reaction
mechanism of the addition of fluoroarenes to Mg–Mg bonds has been determined as a …

Reduction of a variety of extremely bulky amido Group 12 metal halide complexes,[LMX
(THF) 0, 1](L= amide; M= Zn, Cd, or Hg; X= halide) with a magnesium (I) dimer gave a …

The chemistry of stable low oxidation state group 2 metal compounds was initiated in 2007
and has since expanded rapidly, yielding many surprises. Here the author outlines …

The field of heterobimetallic chemistry has rapidly expanded over the last decade. In
addition to their interesting structural features, heterobimetallic structures have been found …

The reaction of the copper (I) β-diketiminate copper complex {(Cu (BDIMes)) 2 (μ-
C6H6)}(BDIMes= N, N′-bis (2, 4, 6-trimethylphenyl) pentane-2, 4-diiminate) with the low …

The synthesis of the first heteroleptic, two-coordinate FeI complex IPr–Fe–N (SiMe3) DIPP
(1)(IPr= 1, 3-bis (2, 6-diisopropylphenyl) imidazol-2-ylidene; DIPP= 2, 6-i Pr2–C6H3) is …