Conspectus Boron heterocycles represent an important subset of heteroatom-incorporated
rings, attracting attention from organic, inorganic, and materials chemists. The empty pz …

Nanoarchitectonics, as a post-nanotechnology concept, constructs functional materials and
structures using nanounits of atoms, molecules, and nanomaterials as materials. With the …

Selective and site-specific boron-doping of polycyclic aromatic hydrocarbon frameworks
often give rise to redox and/or photophysical properties that are not easily accessible with …

Helical nanographenes (NGs) have attracted increasing attention recently because of their
intrinsic chirality and exotic chiroptical properties. However, the efficient synthesis of …

Atomically precise synthesis of three-dimensional boron–nitrogen (BN)-based helical
structures constitutes an undeveloped field with challenges in synthetic chemistry. Herein …

The development of chiral compounds with enhanced chiroptical properties is an important
challenge to improve device applications. To that end, an optimization of the electric and …

Chirality is a fundamental molecular property that plays a crucial role in biophysics and drug
design. Optical circular dichroism (OCD) is a well-established chiral spectroscopic probe in …

Expanded azahelicenes, as heteroanalogues of helically chiral helicenes, hold significant
potential for chiroptical materials. Nevertheless, their investigation and research have …

The recent successful preparation of infinitene has sparked widespread attention due to its
aesthetic appeal and synthetic challenge. Spectroscopic measurements and follow-up …

Molecular topology synthesis of polycyclic aromatic hydrocarbons (PAHs) with diradical
character takes root in intramolecular coupling breakthrough. Herein, we report selective Mn …