A detailed chemical kinetic mechanism has been developed and used to study the oxidation
of iso-octane in a jet-stirred reactor, flow reactors, shock tubes and in a motored engine …

The C2H5•+ O2 reaction, central to ethane oxidation and thus of fundamental importance to
hydrocarbon combustion chemistry, has been examined in detail via highly sophisticated …

Global atmospheric models play a key role in international assessments of the human
impact on global climate and air pollution. To increase the accuracy and facilitate …

Decades of research on the autooxidation of organic compounds have provided
fundamental and practical insights into these processes; however, the structure of many key …

This is the eighth in a series of evaluated sets of rate constants and photochemical cross
sections compiled by the NASA Panel for Data Evaluation. The primary application of the …

The optical properties of point defects are frequently the most important parameter in
applications of glassy silica. They are relatively easy to measure on standard …

Ab initio calculations were performed on CH3CH2OOH, CH3CHClOOH, and CH3CCl2OOH
molecules using the Gaussian92 system of programs. Geometries of stable rotational …

A detailed chemical kinetic model for homogeneous combustion of the light hydrocarbon
fuels CH4 and C2H6 in the intermediate temperature range roughly 500–1100 K, and …

The kinetics and mechanism of the reactions CCl3O2+ CCl3O2→ 2CCl3O+ O2 (1),
CHCl2O2+ CHCl2O2→ 2CHCl2O+ O2 (2a), CHCl2O2+ CHCl2O2→ CHCl2OH+ CCl2O+ O2 …

Ambient concentrations of the hydroxyl (OH), hydroperoxyl (HO2), and total peroxy (ΣRO2)
radicals were measured as part of the Tropospheric OH Photochemistry Experiment at Idaho …