The merger of photoredox catalysis with transition metal catalysis, termed
metallaphotoredox catalysis, has become a mainstay in synthetic methodology over the past …

Oximes are valuable synthetic building blocks with reactivity modes that enable their use in
diverse methodologies, from cycloadditions to bioconjugation. Their reactivity towards …

Alkylboronic pinacol esters (APEs) are highly versatile reagents in organic synthesis.
However, the direct generation of alkyl radicals from commonly used, bench-stable APEs …

Photoredox catalysis in water has been receiving increasing attention due to its merits of
being environment friendly, inexpensive, and safe. However, efficient approaches to …

A nitrogen‐centered radical strategy for the preparation of 3‐acylated spiro [4, 5] trienones
via visible‐light‐mediated acylation/ipso‐cyclization of alkynes with acyl oxime esters is …

Herein we report a chromium-catalyzed reductive allylic defluorinative acylation of
trifluoromethyl substituted alkenes with acyl oxime esters as the acylating agents, allowing …

A convenient and efficient visible-light-induced tandem acylation/cyclization of N-
propargylindoles with aryl-or alkyl-substituted acyl oxime esters for the synthesis of 2-acyl …

Heterocyclic compounds, especially oxygen-containing heterocyclic compounds, are crucial
moieties in bioactive compounds and drug leads. Substituted chroman-4-ones are a kind of …

The functionalization of C–H bonds has become a major thread of research in organic
synthesis that can be assessed from different angles, for instance depending on the type of …

A nitrogen-centered radical-mediated carbon–carbon bond cleavage strategy is described
to synthesize functionalized 3-acylcoumarins. The strategy is enabled by the visible-light …