Atomic and molecular data for spacecraft re-entry plasmas

R Celiberto, I Armenise, M Cacciatore… - Plasma Sources …, 2016 - iopscience.iop.org
The modeling of atmospheric gas, interacting with the space vehicles in re-entry conditions
in planetary exploration missions, requires a large set of scattering data for all those …

Coarse-grain model for internal energy excitation and dissociation of molecular nitrogen

TE Magin, M Panesi, A Bourdon, RL Jaffe… - Chemical Physics, 2012 - Elsevier
A rovibrational collisional coarse-grain model has been developed to reduce a detailed
mechanism for the internal energy excitation and dissociation processes behind a strong …

Reactive, inelastic, and dissociation processes in collisions of atomic oxygen with molecular nitrogen

F Esposito, I Armenise - The Journal of Physical Chemistry A, 2017 - ACS Publications
We report the results of detailed calculations of reactive, inelastic, and dissociative
processes in collisions of atomic oxygen with molecular nitrogen in their respective …

[HTML][HTML] Ab initio-informed maximum entropy modeling of rovibrational relaxation and state-specific dissociation with application to the O2+ O system

M Kulakhmetov, M Gallis, A Alexeenko - The Journal of chemical …, 2016 - pubs.aip.org
Quasi-classical trajectory (QCT) calculations are used to study state-specific ro-vibrational
energy exchange and dissociation in the O 2+ O system. Atom-diatom collisions with energy …

[HTML][HTML] High fidelity modeling of thermal relaxation and dissociation of oxygen

DA Andrienko, ID Boyd - Physics of Fluids, 2015 - pubs.aip.org
A master equation study of vibrational relaxation and dissociation of oxygen is conducted
using state-specific O 2–O transition rates, generated by extensive trajectory simulations …

Impact of fundamental molecular kinetics on macroscopic properties of high-enthalpy flows: The case of hypersonic atmospheric entry

G Colonna, F Bonelli, G Pascazio - Physical Review Fluids, 2019 - APS
Thermochemical nonequilibrium is one of the most challenging issues when dealing with
hypersonic flows experienced by objects (space vehicles, meteoroids, space debris) at …

Advanced models for vibrational and chemical kinetics applied to Mars entry aerothermodynamics

I Armenise, P Reynier, E Kustova - Journal of Thermophysics and Heat …, 2016 - arc.aiaa.org
The paper presents a comparative study of vibrational-chemical kinetics and heat transfer in
carbon dioxide flows under Mars entry conditions for two classes of models: the state-to …

Recombination-assisted nitrogen dissociation rates under nonequilibrium conditions

G Colonna, LD Pietanza, M Capitelli - Journal of Thermophysics and …, 2008 - arc.aiaa.org
ACCURATE characterization of high-enthalpy flows strongly depends on the nonequilibrium
vibrational distributions present in the medium. Two approaches are currently used for …

Quasiclassical trajectory calculations of vibrationally specific dissociation cross-sections and rate constants for the reaction O+ O2 (v)→ 3O

F Esposito, M Capitelli - Chemical physics letters, 2002 - Elsevier
Complete sets of dissociation cross-sections for the process O+ O2 (v)→ 3O for different
rotational temperatures have been calculated by using a quasi-classical trajectory method …

[HTML][HTML] Vibrational energy transfer and dissociation in O2–N2 collisions at hyperthermal temperatures

DA Andrienko, ID Boyd - The Journal of chemical physics, 2018 - pubs.aip.org
Simulation of vibrational energy transfer and dissociation in O 2–N 2 collisions is conducted
using the quasi-classical trajectory method on an ab initio potential energy surface …