A large variety of molecules contain large amplitude motions (LAMs), inter alia internal rotation and inversion tunneling, resulting in tunneling splittings in their rotational spectrum …
NA Seifert, K Prozument, MJ Davis - The Journal of Chemical Physics, 2021 - pubs.aip.org
The use of computational optimal transport is investigated as a tool for comparing two molecular spectra. Unlike other techniques for comparing molecular spectra in a pattern …
F Xie, X Ng, NA Seifert, J Thomas, W Jäger… - The Journal of Chemical …, 2018 - pubs.aip.org
The conformational landscape of tetrahydro-2-furoic acid (THFA), a chiral carboxylic acid which is often used as a precursor in syntheses of pharmaceuticals, was investigated using …
NT Moon, AJ Duerden, TMC McFadden… - The Journal of …, 2023 - ACS Publications
Silacyclohex-2-ene and 1, 1-difluorosilacyclohex-2-ene have been synthesized, and the chirped-pulse, Fourier-transform microwave spectra of each have been observed and …
Broadband rotational spectroscopy provides a new method by which plasma chemistry can be explored. Molecules and complexes form when precursors within an expanding gas …
The design and performance of a new chirped-pulse Fourier transform microwave (CP- FTMW) spectrometer operating from 25 to 40GHz (Ka-band) is presented. This spectrometer …
SA Cooke, P Ohring - Journal of Spectroscopy, 2013 - Wiley Online Library
Rotational spectroscopy can provide insights of unparalleled precision with respect to the wavefunctions of molecular systems that have relevance in fields as diverse as astronomy …
The pure rotational spectra of 1, 1, 1-trifluoro-2-butanone and its four 13C isotopologues have been studied using the new chirped-pulsed Fourier transform microwave spectrometer …
ST Shipman, BH Pate - Handbook of High‐resolution …, 2011 - Wiley Online Library
We discuss the design principles and performance of a true broadband chirped‐pulse Fourier transform microwave spectrometer capable of operation from 800 MHz to 18.5 GHz …