Atropisomers with axial and point chirality: Synthesis and applications

XF Bai, YM Cui, J Cao, LW Xu - Accounts of Chemical Research, 2022 - ACS Publications
Conspectus Enantiopure atropisomers have become increasingly important in asymmetric
synthesis and catalysis, pharmaceutical science, and material science since the discovery of …

Chiral organosulfur ligands/catalysts with a stereogenic sulfur atom: applications in asymmetric synthesis

S Otocka, M Kwiatkowska, L Madalinska… - Chemical …, 2017 - ACS Publications
Asymmetric synthesis, in which chiral organocatalysts or metal complexes with chiral ligands
are used, has become the most valuable methodology for the preparation of …

Stereochemical diversity in pyrrolidine synthesis by catalytic asymmetric 1, 3-dipolar cycloaddition of azomethine ylides

J Adrio, JC Carretero - Chemical Communications, 2019 - pubs.rsc.org
The pyrrolidine ring is a privileged structural motif in synthetic and medicinal chemisty. This
review aims to highlight the high versatility of the catalytic asymmetric 1, 3-dipolar …

The discovery of multifunctional chiral P ligands for the catalytic construction of quaternary carbon/silicon and multiple stereogenic centers

F Ye, Z Xu, LW Xu - Accounts of Chemical Research, 2020 - ACS Publications
Conspectus The development of highly effective chiral ligands is a key topic in enhancing
the catalytic activity and selectivity in metal-catalyzed asymmetric synthesis. Traditionally …

[HTML][HTML] Evolution in heterodonor PN, PS and PO chiral ligands for preparing efficient catalysts for asymmetric catalysis. From design to applications

J Margalef, M Biosca, P de la Cruz Sanchez… - Coordination Chemistry …, 2021 - Elsevier
The success of phosphine-oxazoline ligands (PHOX) inspired the progress in P-oxazoline
ligand families by modifying either the ligand backbone, the electronic and/or steric …

Enantioselective silver-catalyzed transformations

H Pellissier - Chemical Reviews, 2016 - ACS Publications
Enantioselective Silver-Catalyzed Transformations | Chemical Reviews ACS ACS Publications
C&EN CAS Find my institution Log In Chemical Reviews ACS Publications. Most Trusted. Most …

Recent advances in the enantioselective 1, 3-dipolar cycloaddition of azomethine ylides and dipolarophiles

B Bdiri, BJ Zhao, ZM Zhou - Tetrahedron: Asymmetry, 2017 - Elsevier
The synthesis of diastereo-and enantiopure heterocyclic molecules via catalytic asymmetric
1, 3-dipolar cycloaddition reaction between azomethine ylides, generated in situ from α …

Recent developments in enantioselective metal‐catalyzed domino reactions

H Pellissier - Advanced Synthesis & Catalysis, 2019 - Wiley Online Library
This review collects the very recent developments in enantioselective metal‐catalyzed
domino reactions published since the beginning of 2016. It illustrates that many types of …

Application of transition metal fluorides in catalysis

AA Tsygankov, AS Kozlov, S Liao, D Chusov - Coordination Chemistry …, 2024 - Elsevier
Transition metal (TM)-based catalysts are indispensable tools in modern organic synthesis.
Although many efficient catalysts based on TMs are already known, further improvement of …

Combined Dynamic Kinetic Resolution and C− H Functionalization for Facile Synthesis of Non‐Biaryl‐Atropisomer‐Type Axially Chiral Organosilanes

Z Li, X Wang, YM Cui, JH Ma, LL Fang… - … A European Journal, 2021 - Wiley Online Library
Although asymmetric C− H functionalization has been available for the synthesis of
structurally diverse molecules, catalytic dynamic kinetic resolution (DKR) approaches to …