Multivalency as a chemical organization and action principle

C Fasting, CA Schalley, M Weber… - Angewandte Chemie …, 2012 - Wiley Online Library
Multivalent interactions can be applied universally for a targeted strengthening of an
interaction between different interfaces or molecules. The binding partners form cooperative …

The surface site interaction point approach to non-covalent interactions

MC Storer, CA Hunter - Chemical Society Reviews, 2022 - pubs.rsc.org
The functional properties of molecular systems are generally determined by the sum of many
weak non-covalent interactions, and therefore methods for predicting the relative …

Multivalenz als chemisches Organisations‐und Wirkprinzip

C Fasting, CA Schalley, M Weber, O Seitz… - Angewandte …, 2012 - Wiley Online Library
Multivalente Wechselwirkungen können universell zur gezielten Bindungsverstärkung
zwischen verschiedenen Grenzflächen oder Molekülen genutzt werden. Die …

Stepwise effective molarities in porphyrin oligomer complexes: preorganization results in exceptionally strong chelate cooperativity

HJ Hogben, JK Sprafke, M Hoffmann… - Journal of the …, 2011 - ACS Publications
Complexes of zinc porphyrin oligomers with multivalent ligands can be denatured by adding
a large excess of a monodentate ligand, such as quinuclidine. We have used denaturation …

Chelate cooperativity and spacer length effects on the assembly thermodynamics and kinetics of divalent pseudorotaxanes

W Jiang, K Nowosinski, NL Löw… - Journal of the …, 2012 - ACS Publications
Homo-and heterodivalent crown-ammonium pseudorotaxanes with different spacers
connecting the two axle ammonium binding sites have been synthesized and characterized …

High‐Fidelity Noncovalent Synthesis of Hydrogen‐Bonded Macrocyclic Assemblies

C Montoro‐García, J Camacho‐García… - Angewandte …, 2015 - Wiley Online Library
A hydrogen‐bonded cyclic tetramer is assembled with remarkably high effective molarities
from a properly designed dinucleoside monomer. This self‐assembled species exhibits an …

A molecular replication process drives supramolecular polymerization

Y Feng, D Philp - Journal of the American Chemical Society, 2021 - ACS Publications
Supramolecular polymers are materials in which the connections between monomers in the
polymer main chain are non-covalent bonds. This area has seen rapid expansion in the last …

Hydrogen‐Bonded Macrocyclic Supramolecular Systems in Solution and on Surfaces

MJ Mayoral, N Bilbao… - ChemistryOpen, 2016 - Wiley Online Library
Cyclization into closed assemblies is the most recurrent approach to realize the noncovalent
synthesis of discrete, well‐defined nanostructures. This review article particularly focuses on …

Conformationally adaptable macrocyclic receptors for ditopic anions: analysis of chelate cooperativity in aqueous containing media

SN Berry, L Qin, W Lewis, KA Jolliffe - Chemical Science, 2020 - pubs.rsc.org
The effect of chelate cooperativity on the binding of several ditopic anions to two
tetrathiourea macrocycles has been analysed in competitive solvent mixtures (H2O: DMSO …

Cooperative duplex formation by synthetic H-bonding oligomers

AE Stross, G Iadevaia, CA Hunter - Chemical Science, 2016 - pubs.rsc.org
A series of flexible oligomers equipped with phenol H-bond donors and phosphine oxide H-
bond acceptors have been synthesised using reductive amination chemistry. H-bonding …