P-Stereogenic Phosphorus Ligands in Asymmetric Catalysis

T Imamoto - Chemical reviews, 2024 - ACS Publications
Chiral phosphorus ligands play a crucial role in asymmetric catalysis for the efficient
synthesis of useful optically active compounds. They are largely categorized into two …

Which metals are green for catalysis? Comparison of the toxicities of Ni, Cu, Fe, Pd, Pt, Rh, and Au salts

KS Egorova, VP Ananikov - Angewandte Chemie International …, 2016 - Wiley Online Library
Environmental profiles for the selected metals were compiled on the basis of available data
on their biological activities. Analysis of the profiles suggests that the concept of toxic heavy …

Applied hydroformylation

R Franke, D Selent, A Börner - Chemical reviews, 2012 - ACS Publications
Hydroformylation is the addition of synthesis gas (“syngas”), a mixture of CO and H2, to
olefins in the presence of a catalyst under the formation of aldehydes. Hydrogen (“hydro”) …

Metal–metal bonds in catalysis

IG Powers, C Uyeda - Acs Catalysis, 2017 - ACS Publications
Transition metals can assemble to form multinuclear complexes by engaging in direct metal-
to-metal interactions. Metal–metal covalent bonds provide a large perturbation in electronic …

Phosphine− phosphinite and phosphine− phosphite ligands: Preparation and applications in asymmetric catalysis

H Fernandez-Perez, P Etayo, A Panossian… - Chemical …, 2011 - ACS Publications
Phosphine−Phosphinite and Phosphine−Phosphite Ligands: Preparation and Applications in
Asymmetric Catalysis | Chemical Reviews ACS ACS Publications C&EN CAS Find my institution …

Catalytic enantioselective functionalization of unactivated terminal alkenes

JR Coombs, JP Morken - Angewandte Chemie International …, 2016 - Wiley Online Library
Terminal alkenes are readily available functional groups which appear in α‐olefins
produced by the chemical industry, and they appear in the products of many contemporary …

Water in N-heterocyclic carbene-assisted catalysis

E Levin, E Ivry, CE Diesendruck, NG Lemcoff - Chemical reviews, 2015 - ACS Publications
Water is one of the most abundant molecules on earth. It is inexpensive, especially when
compared to organic solvents, nonflammable, and nontoxic, it has a large heat capacity, and …

Alternative metals for homogeneous catalyzed hydroformylation reactions

J Pospech, I Fleischer, R Franke… - Angewandte Chemie …, 2013 - Wiley Online Library
Transition‐metal‐catalyzed hydroformylation reactions constitute one of the most powerful
tools for C C bond formation in organic synthesis and represent an outstanding example of …

[HTML][HTML] Transition-metal catalyzed asymmetric reactions under continuous flow from 2015 to early 2020

J Liao, S Zhang, Z Wang, X Song, D Zhang… - Green Synthesis and …, 2020 - Elsevier
During last two decades, transition-metal catalyzed asymmetric reactions under continuous
flow system have attracted a widespread attention. With its prominent advantages including …

Phosphite-containing ligands for asymmetric catalysis

PWNM Leeuwen, PCJ Kamer, C Claver… - Chemical …, 2011 - ACS Publications
Discovering efficient methods for gaining access to enantiomerically pure compounds in the
development of pharmaceuticals, agrochemicals, and flavors has been a great challenge for …