Organic carbonates are important and valuable building blocks in synthetic chemistry.
Among them, vinylene carbonate (VC) has emerged as a promising coupling partner to …

Recently, vinylene carbonate has been developed as a powerful synthon in transition metal‐
catalyzed C− H bond activation/cyclization reactions. This review introduces recent progress …

Here we report a novel Rh-catalyzed C− H/C− H alkenylation of N-arylmethanimines with
vinylene carbonate acting as a vinylene unit. Forty examples of C3, C4-nonsubstituted …

The rhodium (III)‐catalyzed C− H bond activation and vinylene transfer of enaminones with
vinylene carbonate have been proposed for the synthesis of substituted 1‐hydroxy‐2 …

Benzofuran is a privileged structure in many bioactive compounds; however, the controlled
synthesis of C2, C3-nonsubstituted benzofurans has been scarce. In particular, cumbersome …

Chemical transformation with vinylene carbonate as an emerging synthetic unit has recently
attracted considerable attention. This report is a novel conversion pattern with vinylene …

A convenient and effective method of ruthenium‐catalyzed C− H/N− H annulations using
vinylene carbonate as oxidizing acetylene surrogate has been disclosed. This method is …

The ruthenium‐catalyzed C7‐formylmethylation or sequential acetalization of indolines with
vinylene carbonate has been realized under simple and easy‐to‐operate reaction systems …

A rhodium-catalyzed cyclization of azobenzenes and vinylene carbonate via C–H bond
activation to construct indazolo [2, 3-a] quinolines has been developed. This protocol offers …

In this study, Rh (III)‐catalyzed C− H bifunctionalization and direct vinylene annulation of
sulfoxonium ylides and N‐carbamoylindoles with vinylene carbonate was accomplished …